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author:

Zhang, Qi (Zhang, Qi.) [1] | Muhammad, Munira Taj (Muhammad, Munira Taj.) [2] | Chiou, Mong-Feng (Chiou, Mong-Feng.) [3] | Jiao, Yihang (Jiao, Yihang.) [4] | Bao, Hongli (Bao, Hongli.) [5] | Li, Yajun (Li, Yajun.) [6]

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Scopus SCIE

Abstract:

The regioselective synthesis of fluorinated allenes via a metal-free 1,4-fluoroamination of 1,3-enynes is presented. This method employs commercially available N-fluorobenzenesulfonimide serving as both the nitrogen source and the fluorine source, affording access to various tetrasubstituted allenes in a straightforward and atom-economic pathway. Preliminary mechanistic studies and theoretical studies revealed that this reaction might undergo an intimate ion-pair mechanism.

Keyword:

Community:

  • [ 1 ] [Zhang, Qi]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Muhammad, Munira Taj]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Chiou, Mong-Feng]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Jiao, Yihang]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Bao, Hongli]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Li, Yajun]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Zhang, Qi]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Li, Yajun]Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China

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Source :

ORGANIC LETTERS

ISSN: 1523-7060

Year: 2020

Issue: 13

Volume: 22

Page: 5261-5265

6 . 0 0 5

JCR@2020

4 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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