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Abstract:
The title compound, [CdI2(C12H8N2)(2)], consists of two 1,10-phenanthroline (phen) ligands, two I atoms and one Cd atom. The coordination geometry around the Cd atom, which lies on a twofold rotation axis, is slightly distorted octahedral. In the crystal structure, the dihedral angle between the two phen ligands is 89.03 (5)degrees. The crystal packing is stabilized by intermolecular pi-pi interactions of phen rings, with a parallel distance of 3.362 angstrom, a centroid-centroid distance of 3.903 angstrom and a slip distance of 1.983 angstrom, and C - H center dot center dot center dot I hydrogen bonding [I center dot center dot center dot H = 3.091 and 2.990 angstrom].
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
ISSN: 2056-9890
Year: 2007
Volume: 63
Page: M1951-U1478
0 . 5 0 0
JCR@2023
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 3
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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