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author:

Cao, Ming-Lei (Cao, Ming-Lei.) [1] | Fang, Xin (Fang, Xin.) [2] (Scholars:方昕) | Yu, Hai-Yang (Yu, Hai-Yang.) [3] | Wang, Jun-Dong (Wang, Jun-Dong.) [4] (Scholars:王俊东)

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Scopus SCIE

Abstract:

The title compound, [CdI2(C12H8N2)(2)], consists of two 1,10-phenanthroline (phen) ligands, two I atoms and one Cd atom. The coordination geometry around the Cd atom, which lies on a twofold rotation axis, is slightly distorted octahedral. In the crystal structure, the dihedral angle between the two phen ligands is 89.03 (5)degrees. The crystal packing is stabilized by intermolecular pi-pi interactions of phen rings, with a parallel distance of 3.362 angstrom, a centroid-centroid distance of 3.903 angstrom and a slip distance of 1.983 angstrom, and C - H center dot center dot center dot I hydrogen bonding [I center dot center dot center dot H = 3.091 and 2.990 angstrom].

Keyword:

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 王俊东

    [Wang, Jun-Dong]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

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Source :

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

ISSN: 2056-9890

Year: 2007

Volume: 63

Page: M1951-U1478

0 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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