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Abstract:
The construction of heterojunctions is beneficial to improve the separation efficiency of photogenerated electron-hole pairs, so as to enhance the activity of photocatalysts. Herein, NiS thin layer covered CdS nanorods (NiS/CdS) were synthesized by a two-step hydrothermal approach. Under the irradiation of visible light, the optimal NiS/CdS covered heterojunctions showed high photocatalytic stability and excellent hydrogen evolution rate up to 401.7 mmol g(-1) h(-1), which is higher than that of most CdS-based photocatalysts. The apparent quantum efficiency of NiS/CdS at 420 nm was 1.5%. The formation of NiS/CdS heterojunctions with large intimate contact area leads to strong interfacial coupling between NiS thin layers and CdS nanorods. This promotes the separation and migration of photoinduced electron-hole pairs and provides more active sites for redox reactions, thus improving the activity of photocatalysts. This work presents new ideas for the design of high-performance photocatalysts for H-2 production.
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NEW JOURNAL OF CHEMISTRY
ISSN: 1144-0546
Year: 2020
Issue: 44
Volume: 44
Page: 19083-19090
3 . 5 9 1
JCR@2020
2 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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