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author:

Chen, Zhaohui (Chen, Zhaohui.) [1] | Cheng, Chuchu (Cheng, Chuchu.) [2] | Xing, Fangshu (Xing, Fangshu.) [3] | Huang, Caijin (Huang, Caijin.) [4] (Scholars:黄彩进)

Indexed by:

SCIE

Abstract:

The construction of heterojunctions is beneficial to improve the separation efficiency of photogenerated electron-hole pairs, so as to enhance the activity of photocatalysts. Herein, NiS thin layer covered CdS nanorods (NiS/CdS) were synthesized by a two-step hydrothermal approach. Under the irradiation of visible light, the optimal NiS/CdS covered heterojunctions showed high photocatalytic stability and excellent hydrogen evolution rate up to 401.7 mmol g(-1) h(-1), which is higher than that of most CdS-based photocatalysts. The apparent quantum efficiency of NiS/CdS at 420 nm was 1.5%. The formation of NiS/CdS heterojunctions with large intimate contact area leads to strong interfacial coupling between NiS thin layers and CdS nanorods. This promotes the separation and migration of photoinduced electron-hole pairs and provides more active sites for redox reactions, thus improving the activity of photocatalysts. This work presents new ideas for the design of high-performance photocatalysts for H-2 production.

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Community:

  • [ 1 ] [Chen, Zhaohui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 2 ] [Cheng, Chuchu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 3 ] [Xing, Fangshu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 4 ] [Huang, Caijin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

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Source :

NEW JOURNAL OF CHEMISTRY

ISSN: 1144-0546

Year: 2020

Issue: 44

Volume: 44

Page: 19083-19090

3 . 5 9 1

JCR@2020

2 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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