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author:

Wang, Qiong (Wang, Qiong.) [1] | Zu, Fengshuo (Zu, Fengshuo.) [2] | Caprioglio, Pietro (Caprioglio, Pietro.) [3] | Wolff, Christian M. (Wolff, Christian M..) [4] | Stolterfoht, Martin (Stolterfoht, Martin.) [5] | Li, Meng (Li, Meng.) [6] | Turren-Cruz, Silver-Hamill (Turren-Cruz, Silver-Hamill.) [7] | Koch, Norbert (Koch, Norbert.) [8] | Neher, Dieter (Neher, Dieter.) [9] | Abate, Antonio (Abate, Antonio.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Although SnO2 has been reported to give high efficiencies of over 20% for organic-inorganic perovskite solar cells and has been frequently used in perovskite tandem solar cells, very few contributions have explored its feasibility in inorganic perovskite solar cells (IPSCs). Inorganic perovskites with a wide bandgap tunable from 1.7 to 2.0 eV are promising candidates for top cells in tandem structures; development of IPSCs based on SnO2 will greatly benefit their integration into tandem solar cells. We examined SnO2 in comparison to the prevalent TiO2. We found that although SnO2 had a good energy alignment with the inorganic perovskite and exhibited slower nonradiative recombination, the relatively low conduction band minimum energy offset restricted efficient charge extraction. In contrast, TiO2 that had a large energy offset of similar to 400 meV led to a high fill factor of 78.7% and a state-of-the-art efficiency of 14.2% for IPSCs with a bandgap of 1.93 eV.

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Community:

  • [ 1 ] [Wang, Qiong]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany
  • [ 2 ] [Caprioglio, Pietro]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany
  • [ 3 ] [Li, Meng]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany
  • [ 4 ] [Turren-Cruz, Silver-Hamill]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany
  • [ 5 ] [Abate, Antonio]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany
  • [ 6 ] [Abate, Antonio]Univ Naples Federioco II, Dept Chem Mat & Prod Engn, I-80125 Naples, Italy
  • [ 7 ] [Abate, Antonio]Fuzhou Univ, Inst Adv Energy Mat, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Zu, Fengshuo]Humboldt Univ, Inst Phys, D-12489 Berlin, Germany
  • [ 9 ] [Koch, Norbert]Humboldt Univ, Inst Phys, D-12489 Berlin, Germany
  • [ 10 ] [Zu, Fengshuo]Humboldt Univ, IRIS Adlershof, D-12489 Berlin, Germany
  • [ 11 ] [Koch, Norbert]Humboldt Univ, IRIS Adlershof, D-12489 Berlin, Germany
  • [ 12 ] [Caprioglio, Pietro]Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
  • [ 13 ] [Wolff, Christian M.]Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
  • [ 14 ] [Stolterfoht, Martin]Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
  • [ 15 ] [Neher, Dieter]Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
  • [ 16 ] [Li, Meng]Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
  • [ 17 ] [Koch, Norbert]Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China

Reprint 's Address:

  • ANTONIO ABATE

    [Wang, Qiong]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany;;[Abate, Antonio]Helmholtz Zentrum Berlin Mat & Energie, Grp Act Mat & Inteifaces Stable Perovskite Solar, D-12489 Berlin, Germany;;[Abate, Antonio]Univ Naples Federioco II, Dept Chem Mat & Prod Engn, I-80125 Naples, Italy;;[Abate, Antonio]Fuzhou Univ, Inst Adv Energy Mat, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

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Source :

ACS ENERGY LETTERS

ISSN: 2380-8195

Year: 2020

Issue: 7

Volume: 5

Page: 2343-2348

2 3 . 1 0 1

JCR@2020

1 9 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 20

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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