In　this　study,　fully　concentrated　Eu3+-based　Na3Eu(VO4)(2)vanadate　phosphor　was　synthesized　by　solid-state　reaction　process.　The　as-obtained　product　presented　a　single　monoclinic　phase　with　the　space　group　ofCc(9)　and　rod　shape　with　micron　size,　as　revealed　by　X-ray　diffraction　pattern　and　scanning　electron　microscope.　Their　luminescence　performances　were　investigated　by　the　excitation　and　emission　spectra,　temperature-dependent　photoluminescence　spectra.　At　the　excitation　of　395　nm,　they　displayed　a　strong　red　emission　at　620　nm　and　the　Gd(3+)and　La(3+)ions　incorporation　did　not　lead　to　luminescent　quenching　in　this　Na3Eu(VO4)(2)phosphor.　When　the　temperature　was　as　high　as　420　K,　the　emission　intensity　kept　84%　of　the　initial　value　at　303　K,　which　implied　the　Na3Eu(VO4)(2)phosphors　had　excellent　thermal　stability.　Further,　the　activation　energy　(E-a)　was　calculated　to　be　0.326　eV.　Meanwhile,　the　quantum　yield　of　this　phosphor　was　as　high　as　70.6%.　Finally,　by　coating　the　mixtures　of　red　phosphors　Na3Eu(VO4)(2),　commercial　green　phosphors　(Sr,　Ba)(2)SiO4:Eu(2+)and　blue　phosphors　BaMgAl10O17:Eu(2+)on　the　surface　of　NUV　chip　(395　nm),　a　LED　lamp　was　obtained　and　exhibited　white　light　with　good　color　rendering　index　of　93.　These　results　exhibited　the　commercialized　prospect　of　Na3Eu(VO4)(2)compound　as　a　red　phosphor　in　the　field　of　solid-state　lighting.