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author:

Wang, Ying (Wang, Ying.) [1] | Shang, Xiaotong (Shang, Xiaotong.) [2] | Shen, Jinni (Shen, Jinni.) [3] (Scholars:沈锦妮) | Zhang, Zizhong (Zhang, Zizhong.) [4] (Scholars:张子重) | Wang, Debao (Wang, Debao.) [5] | Lin, Jinjin (Lin, Jinjin.) [6] | Wu, Jeffrey C. S. (Wu, Jeffrey C. S..) [7] | Fu, Xianzhi (Fu, Xianzhi.) [8] (Scholars:付贤智) | Wang, Xuxu (Wang, Xuxu.) [9] (Scholars:王绪绪) | Li, Can (Li, Can.) [10]

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Scopus SCIE

Abstract:

The stoichiometric photocatalytic reaction of CO2 with H2O is one of the great challenges in photocatalysis. Here, we construct a Cu2O-Pt/SiC/IrOx composite by a controlled photodeposition and then an artificial photosynthetic system with Nafion membrane as diaphragm separating reduction and oxidation half-reactions. The artificial system exhibits excellent photocatalytic performance for CO2 reduction to HCOOH and H2O oxidation to O-2 under visible light irradiation. The yields of HCOOH and O-2 meet almost stoichiometric ratio and are as high as 896.7 and 440.7 mu molg(-1)h(-1), respectively. The high efficiencies of CO2 reduction and H2O oxidation in the artificial system are attributed to both the direct Z-scheme electronic structure of Cu2O-Pt/SiC/IrOx and the indirect Z-scheme spatially separated reduction and oxidation units, which greatly prolong lifetime of photogenerated electrons and holes and prevent the backward reaction of products. This work provides an effective and feasible strategy to increase the efficiency of artificial photosynthesis.

Keyword:

Community:

  • [ 1 ] [Wang, Ying]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 2 ] [Shang, Xiaotong]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 3 ] [Shen, Jinni]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zhang, Zizhong]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Jinjin]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wang, Xuxu]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 8 ] [Wang, Ying]Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Inorgan Synthet & Appl Chem, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China
  • [ 9 ] [Wang, Debao]Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Inorgan Synthet & Appl Chem, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China
  • [ 10 ] [Wu, Jeffrey C. S.]Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan
  • [ 11 ] [Li, Can]Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Reprint 's Address:

  • 张子重 王绪绪

    [Zhang, Zizhong]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China;;[Wang, Xuxu]Fuzhou Univ, Coll Chem, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China;;[Wu, Jeffrey C. S.]Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan;;[Li, Can]Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

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Source :

NATURE COMMUNICATIONS

ISSN: 2041-1723

Year: 2020

Issue: 1

Volume: 11

1 4 . 9 1 9

JCR@2020

1 4 . 7 0 0

JCR@2023

ESI Discipline: MULTIDISCIPLINARY;

ESI HC Threshold:420

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 306

SCOPUS Cited Count: 286

ESI Highly Cited Papers on the List: 19 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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