Volatile　organic　compounds　(VOCs)　are　perceived　as　serious　pollutants　due　to　their　great　threat　to　both　environment　and　human　health.　Recovery　and　removal　of　VOCs　is　of　great　significance.　Herein,　novel　MOF-199　derived　porous　carbon　materials　(MC-T-n)　were　prepared　by　using　MOF-199　as　precursor,　glucose　as　additional　carbon　source　and　KOH　as　activator,　and　then　characterized.　Adsorption　performance　of　MC-T-n　materials　for　benzene　vapor　was　investigated.　Isotherms　of　MC-T-n　samples　towards　benzene　and　water　vapor　were　measured.　The　adsorption　selectivities　of　benzene/water　were　estimated　by　DIH　(difference　of　the　isosteric　heats)　equation.　Results　indicated　that　BET　surface　area　and　pore　volume　of　MC-T-n　materials　reached　separately　2320　m(2)/g　and　1.05　m(3)/g.　Benzene　adsorption　capacity　of　MC-T-n　materials　reached　as　high　as　12.8　mmol/g　at　25　degrees　C,　outperforming　MOF-199　and　some　conventional　adsorbents.　Moreover,　MC-T-n　materials　presented　type-V　isotherms　of　water　vapor,　suggesting　their　excellent　water　resistance.　The　isosteric　heats　of　benzene　adsorption　on　MC-500-6　were　much　greater　than　that　of　water　adsorption,　leading　to　a　preferential　adsorption　for　C6H6　over　H2O.　The　adsorption　selectivity　of　C6H6/H2O　on　MC-500-6　reached　up　to　16.3　superior　to　some　previously　reported　MOFs.　Therefore,　MC-500-6　was　a　promising　candidate　for　VOC　adsorption　and　seperation.　This　study　provides　a　strong　foundation　for　MOF　derived　porous　carbons　as　adsorbents　for　VOC　removal.