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author:

Yang, Can (Yang, Can.) [1] (Scholars:阳灿) | Li, Run (Li, Run.) [2] | Zhang, Kai A., I (Zhang, Kai A., I.) [3] | Lin, Wei (Lin, Wei.) [4] (Scholars:林伟) | Landfester, Katharina (Landfester, Katharina.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] (Scholars:王心晨)

Indexed by:

Scopus SCIE

Abstract:

Large-scale photochemical synthesis of high value chemicals under mild conditions is an ideal method of green chemical production. However, a scalable photocatalytic process has been barely reported due to the costly preparation, low stability of photosensitizers and critical reaction conditions required for classical photocatalysts. Here, we report the merging of flow chemistry with heterogeneous photoredox catalysis for the facile production of high value compounds in a continuous flow reactor with visible light at room temperature in air. In the flow reactor system, polymeric carbon nitrides, which are cheap, sustainable and stable heterogeneous photocatalysts, are immobilized onto glass beads and fibers, demonstrating a highly flexible construction possibility for devices of the photocatalytic materials. As an example of the production of high value chemicals, important chemical structures such as cyclobutanes, which are basic building blocks for many pharmaceutical compounds, like magnosalin, are synthesized in flow with high catalytic efficiency and stability.

Keyword:

Community:

  • [ 1 ] [Yang, Can]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 2 ] [Lin, Wei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 4 ] [Li, Run]Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
  • [ 5 ] [Zhang, Kai A., I]Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
  • [ 6 ] [Landfester, Katharina]Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany

Reprint 's Address:

  • 王心晨

    [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China;;[Zhang, Kai A., I]Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany

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Source :

NATURE COMMUNICATIONS

ISSN: 2041-1723

Year: 2020

Issue: 1

Volume: 11

1 4 . 9 1 9

JCR@2020

1 4 . 7 0 0

JCR@2023

ESI Discipline: MULTIDISCIPLINARY;

ESI HC Threshold:420

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 200

SCOPUS Cited Count: 99

ESI Highly Cited Papers on the List: 14 Unfold All

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  • 2022-11
  • 2022-9

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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