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Abstract：
In consideration of the strong oxidizing power of hypochlorite (ClO-), which could cleave C=N moiety, a cyclometalated iridium (III) complex (Ir-Ts) modified hydrazide group as the response unit was synthesized to sensitively and selectively detect ClO- under neutral condition. Upon addition of ClO-, a 21-fold emission enhancement at 574 nm was observed and phosphorescent product was formed due to the cleavage of C=N moiety. The probe Ir-Ts displayed rapid response ( ＜ 15 s) and high selectivity toward ClO- with a low detection limit of 86 nM. More importantly, bioimaging of ClO- was further studied in living cells.
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ANALYTICAL BIOCHEMISTRY
ISSN： 0003-2697
Year： 2020
Volume： 592
3 . 3 6 5
JCR@2020
2 . 6 0 0
JCR@2023
ESI Discipline： BIOLOGY & BIOCHEMISTRY;
ESI HC Threshold：156
JCR Journal Grade：2
CAS Journal Grade：3
Cited Count：
WoS CC Cited Count： 6
SCOPUS Cited Count： 9
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 2
Affiliated Colleges：
