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author:

Gao, Haifeng (Gao, Haifeng.) [1] | Zhai, Chunyang (Zhai, Chunyang.) [2] | Fu, Nianqing (Fu, Nianqing.) [3] | Du, Yukou (Du, Yukou.) [4] | Yu, Kevin (Yu, Kevin.) [5] | Zhu, Mingshan (Zhu, Mingshan.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

The combination of different semiconductors to form a heterojunction plays an important role for exploring new visible-light-driven electrocatalysts. Herein, a two-dimensional (2D) Bi2WO6/La-2 Ti2O7 (LTO) heterojunction has been synthesized and to be as carrier of Pt nanoparticles. Subsequently, electrocatalytic activity and stability of the as-obtained Pt-Bi2WO6/LTO has been evaluated in methanol oxidation reaction (MOR) under the action of visible light and electricity. Results indicate that Pt-Bi2WO6/LTO sample displays excellent catalytic performance and stability with assistance from visible light. Under identical conditions, the current intensity of MOR on the Pt-Bi2WO6/LTO modified electrode is found to reach 1409 mA mgF(pt)(-1) , which is 3.92 times higher than the measured Pt-Bi2WO6 modified electrode (359.8 mA mgFpt(-1) ). In addition, the current density of MOR on Pt-Bi2WO6/LTO electrode decreases by 2.85% after scanning for 300 cycles. Furthermore, Pt-Bi2WO6/LTO is 6.99 times more resistant to poisoning than the Pt-Bi2WO6 electrode determines by chronopotentiometry under visible light illumination. The presented results indicate that a Pt-Bi2WO6/LTO nanocomposite is a viable alternative photo-electric catalyst, providing a potential new basis for the future development of catalysts in fuel cell reactions. (C) 2019 Elsevier Inc. All rights reserved.

Keyword:

Bismuth tungstate Fuel cell reaction La2Ti2O7 Methanol oxidation Photoelectrocatalyst

Community:

  • [ 1 ] [Gao, Haifeng]Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China
  • [ 2 ] [Zhai, Chunyang]Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China
  • [ 3 ] [Zhu, Mingshan]Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China
  • [ 4 ] [Zhai, Chunyang]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 5 ] [Fu, Nianqing]South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Peoples R China
  • [ 6 ] [Du, Yukou]Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
  • [ 7 ] [Yu, Kevin]Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

Reprint 's Address:

  • 待查

    [Zhai, Chunyang]Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China;;[Zhai, Chunyang]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China;;[Fu, Nianqing]South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Peoples R China

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Source :

JOURNAL OF COLLOID AND INTERFACE SCIENCE

ISSN: 0021-9797

Year: 2020

Volume: 561

Page: 338-347

8 . 1 2 8

JCR@2020

9 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 27

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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