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author:

Wang, Huajing (Wang, Huajing.) [1] | Lin, Jinfeng (Lin, Jinfeng.) [2] | Deng, Baoyu (Deng, Baoyu.) [3] | Lin, Tengfei (Lin, Tengfei.) [4] (Scholars:林腾飞) | Lin, Cong (Lin, Cong.) [5] (Scholars:林枞) | Cheng, Yao (Cheng, Yao.) [6] | Wu, Xiao (Wu, Xiao.) [7] (Scholars:吴啸) | Zheng, Xinghua (Zheng, Xinghua.) [8] (Scholars:郑兴华) | Yu, Xing (Yu, Xing.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

A novel photochromic (PC) ferroelectric material, Nd3+-doped K0.5Na0.5NbO3 translucent ceramic, was fabricated by a conventional solid method. The ceramic shows moderate optical transparency due to its dense microstructure, as well as good photoluminescence (PL) properties of up-conversion (UC) emission in the visible region and down-shifting (DS) emission in the near-infrared region. Simultaneously, the colors of all the ceramics turn darker after 365 nm illumination, and then recover to their initial states upon thermal stimulus (210 degrees C, 10 min), exhibiting a typical PC phenomenon. In particular, the effect of the PC behavior on PL lifetimes of Nd3+ was investigated. Multi-mode reversible modulations of various optical behaviors were realized based on the PC behavior, especially for the regulation of near-infrared emission. And the maximum modulation ratios of transmittances, UC or DS PL intensities and luminescence lifetimes are 43.0%, 66.7%, 66.4% and 12.8%, respectively. Owing to high-temperature sintering and Nd3+ substitution in the ceramics, cation and oxygen vacancies appear to produce F ' and V-1 color centers, which are in charge of the PC behavior and corresponding modulations. These results suggest that the ceramics are a promising PC material in visible and near-infrared optical data storage, photo-switches, and optoelectronic devices. Meanwhile, they also provide insights into the applications of rare-earth Nd3+ in other inorganic PC ferroelectric materials.

Keyword:

Community:

  • [ 1 ] [Wang, Huajing]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 2 ] [Lin, Jinfeng]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 3 ] [Deng, Baoyu]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 4 ] [Lin, Tengfei]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 5 ] [Lin, Cong]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 6 ] [Wu, Xiao]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 7 ] [Zheng, Xinghua]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 8 ] [Cheng, Yao]Fujian Inst Res Struct, Fuzhou, Peoples R China
  • [ 9 ] [Yu, Xing]Natl Anal Ctr Iron & Steel, Cent Iron & Steel Res Inst, Beijing, Peoples R China

Reprint 's Address:

  • 林腾飞 吴啸

    [Lin, Tengfei]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China;;[Wu, Xiao]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

Year: 2020

Issue: 7

Volume: 8

Page: 2343-2352

7 . 3 9 3

JCR@2020

5 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 86

SCOPUS Cited Count: 77

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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