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author:

Hao, Yucheng (Hao, Yucheng.) [1] | He, Linbo (He, Linbo.) [2] | Ge, Guangjie (Ge, Guangjie.) [3] | Zhang, Quanzheng (Zhang, Quanzheng.) [4] | Luo, Ningjing (Luo, Ningjing.) [5] | Huang, Shuping (Huang, Shuping.) [6] (Scholars:黄淑萍) | Li, Haijian (Li, Haijian.) [7] | Alekseev, Evgeny, V (Alekseev, Evgeny, V.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Investigation of the Pt-B-O system reveals the first magnesium platinum borate Mg3Pt(BO3)(2)O-2 obtained from the high temperature flux method. The compound crystallizes in the centrosymmetric monoclinic space group C2/m (no. 12) with the lattice parameters of a = 16.8073(8) angstrom, b = 3.10610(1) angstrom, c = 5.2107(2) angstrom, and beta = 90.546(4)degrees (Z = 2). The crystal structure of Mg3Pt(BO3)(2)O-2 is based upon isolated BO3 triangles and PtO6 and MgO6 octahedra. The PtO6 octahedra are connected with each other in an edge-sharing manner forming one dimensional (1D) chains. Each of the PtO6 octahedra links with two BO3 units to form anionic [Pt(BO3)(2)O-2](6-) chains along the b-axis. MgO6 octahedra are arranged in the form of two dimensional (2D) layers. The 2D MgO6 layers are further connected by the anionic [Pt(BO3)2O(2)](6-) chains into the 3D framework structure of Mg3Pt(BO3)(2)O-2. The material was experimentally and theoretically characterized in regards to its optical and spectroscopic properties.

Keyword:

Borates First-principles calculations Optical properties Platinum Single-crystal structure Theoretical studies

Community:

  • [ 1 ] [Hao, Yucheng]Hefei Univ, Dept Chem & Mat Engn, Hefei 230000, Anhui, Peoples R China
  • [ 2 ] [He, Linbo]Hefei Univ, Dept Chem & Mat Engn, Hefei 230000, Anhui, Peoples R China
  • [ 3 ] [Ge, Guangjie]Hefei Univ, Dept Chem & Mat Engn, Hefei 230000, Anhui, Peoples R China
  • [ 4 ] [Zhang, Quanzheng]Hefei Univ, Dept Chem & Mat Engn, Hefei 230000, Anhui, Peoples R China
  • [ 5 ] [Luo, Ningjing]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Huang, Shuping]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Li, Haijian]Xian Modern Chem Res Inst, Natl Key Lab Sci & Technol Combust & Explos, Xian 710065, Shaanxi, Peoples R China
  • [ 8 ] [Alekseev, Evgeny, V]Forschungszentrum Julich, Inst Energy & Climate Res IEK 6, D-52428 Julich, Germany
  • [ 9 ] [Alekseev, Evgeny, V]Rhein Westfal TH Aachen, Inst Kristallog, D-52066 Aachen, Germany
  • [ 10 ] [Huang, Shuping]Fujian Prov Key Lab Theoret & Computat Chem, Xiamen 361005, Fujian, Peoples R China

Reprint 's Address:

  • 黄淑萍

    [Hao, Yucheng]Hefei Univ, Dept Chem & Mat Engn, Hefei 230000, Anhui, Peoples R China;;[Huang, Shuping]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China;;[Alekseev, Evgeny, V]Forschungszentrum Julich, Inst Energy & Climate Res IEK 6, D-52428 Julich, Germany

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Source :

JOURNAL OF SOLID STATE CHEMISTRY

ISSN: 0022-4596

Year: 2020

Volume: 281

3 . 4 9 8

JCR@2020

3 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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