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Abstract:
Investigation of the Pt-B-O system reveals the first magnesium platinum borate Mg3Pt(BO3)(2)O-2 obtained from the high temperature flux method. The compound crystallizes in the centrosymmetric monoclinic space group C2/m (no. 12) with the lattice parameters of a = 16.8073(8) angstrom, b = 3.10610(1) angstrom, c = 5.2107(2) angstrom, and beta = 90.546(4)degrees (Z = 2). The crystal structure of Mg3Pt(BO3)(2)O-2 is based upon isolated BO3 triangles and PtO6 and MgO6 octahedra. The PtO6 octahedra are connected with each other in an edge-sharing manner forming one dimensional (1D) chains. Each of the PtO6 octahedra links with two BO3 units to form anionic [Pt(BO3)(2)O-2](6-) chains along the b-axis. MgO6 octahedra are arranged in the form of two dimensional (2D) layers. The 2D MgO6 layers are further connected by the anionic [Pt(BO3)2O(2)](6-) chains into the 3D framework structure of Mg3Pt(BO3)(2)O-2. The material was experimentally and theoretically characterized in regards to its optical and spectroscopic properties.
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JOURNAL OF SOLID STATE CHEMISTRY
ISSN: 0022-4596
Year: 2020
Volume: 281
3 . 4 9 8
JCR@2020
3 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: