In　this　report,　two　new　binuclear　mixed-valence　(MV)　compounds　and　their　one-electron　oxidation　products,　[MeCpLRu(mu-CN)Fe(dppe)Cp][PF6](n)　(L　=　dppe,　(PPh3)(2))　(n　=　1,　2),　were　synthesized　and　thoroughly　characterized　by　single-crystal　X-ray　diffraction　analysis.　Complexes　1(2+)　and　2(2+)　are　one-electron　oxidation　products　of　1(1+)　and　2(+),　respectively.　The　electronic　absorption　results　indicate　that　there　exists　metal　to　metal　charge　transfer　(MMCT)　in　the　one-electron　oxidation　products,　which　is　strongly　supported　by　the　theoretical　calculations.　Complexes　1(2+)　and　2(2+)　can　be　defined　as　Class　II　MV　compounds.　It　is　found　that　the　MMCT　band　is　obviously　red-shifted　on　going　from　1(2+)　to　2(2+),　because　the　donating　electron　ability　of　(PPh3)(2)　is　stronger　than　that　of　dppe.　(C)　2019　Elsevier　Ltd.　All　rights　reserved.