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author:

Sun, Qian-yu (Sun, Qian-yu.) [1] | Yin, Wan-zhong (Yin, Wan-zhong.) [2] | Cao, Shao-hang (Cao, Shao-hang.) [3] | Yang, Bin (Yang, Bin.) [4] | Sun, Hao-ran (Sun, Hao-ran.) [5] | Tang, Yuan (Tang, Yuan.) [6] | Wang, Dong-hui (Wang, Dong-hui.) [7] | Yao, Jin (Yao, Jin.) [8]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

In this paper, the effect of sodium butyl xanthate (NaBX) adsorption on the surface of bornite at different pH on flotation was studied by adsorption kinetic and thermodynamic. The flotation results demonstrated that the recovery was the highest when pH was 9 in NaBX solution (4x10(-5) mol/L). The adsorption kinetics showed the reaction of NaBX on the bornite conformed to the second order kinetic equation; it belonged to the multimolecular layer adsorption of Freundlich model; the maximum adsorption rate constant was 0.30 g/(10(-6) mol center dot min), and the equilibrium adsorption capacity was 2.70x10(-6) mol/g. Thermodynamic calculation results indicated that the adsorption process was spontaneous chemisorption, and the adsorption products of NaBX on bornite surface were cupric butyl xanthate, ferric butyl xanthate and dixanthogen, which were confirmed by infrared spectrum measurements.

Keyword:

adsorption bornite infrared spectrum kinetics and thermodynamics sodium butyl xanthate

Community:

  • [ 1 ] [Sun, Qian-yu]Tsinghua Univ, Sch Environm, Beijing 100084, Peoples R China
  • [ 2 ] [Sun, Qian-yu]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 3 ] [Yin, Wan-zhong]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 4 ] [Cao, Shao-hang]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 5 ] [Yang, Bin]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 6 ] [Sun, Hao-ran]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 7 ] [Tang, Yuan]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 8 ] [Wang, Dong-hui]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 9 ] [Yao, Jin]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
  • [ 10 ] [Yin, Wan-zhong]Fuzhou Univ, Sch Zijin Min, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 印万忠

    [Sun, Qian-yu]Tsinghua Univ, Sch Environm, Beijing 100084, Peoples R China;;[Sun, Qian-yu]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China;;[Yin, Wan-zhong]Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China;;[Yin, Wan-zhong]Fuzhou Univ, Sch Zijin Min, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF CENTRAL SOUTH UNIVERSITY

ISSN: 2095-2899

CN: 43-1516/TB

Year: 2019

Issue: 11

Volume: 26

Page: 2998-3007

1 . 2 4 9

JCR@2019

3 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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