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author:

Li, Jie (Li, Jie.) [1] | Zhang, Lu (Zhang, Lu.) [2] | Li, Jiawei (Li, Jiawei.) [3] | An, Ping (An, Ping.) [4] | Hou, Yidong (Hou, Yidong.) [5] (Scholars:侯乙东) | Zhang, Jinshui (Zhang, Jinshui.) [6] (Scholars:张金水)

Indexed by:

EI Scopus SCIE

Abstract:

Transition metal nanoparticles encapsulated in carbon nanostructures (M@Carbon, M = Fe, Co, Ni, et al.) exhibit excellent catalytic performance toward the hydrogen evolution reaction (HER). However, their application as HER cocatalysts for photocatalytic hydrogen production is greatly hampered by their random growth nanostructures with rather big overall size (e.g., nanotube structure with length of 5-50 mu m). Herein, a nanoconfined assembly strategy is well developed for the textural engineering of Co@Carbon with an optimized nanostructure for photocatalysis. The spatial compartmentalization and physical confinement of precursors within the silica aerogel kinetically control the core-shell nanostructure assembly and facilitates the synthesis of Co@Carbon with controllable morphology and reduced particle size (similar to 30 nm), making Co@Carbon a promising HER cocatalyst for photocatalytic hydrogen evolution. Furthermore, this nanoconfined assembly strategy is a general approach that can be widely applied for textural engineering of other transition metal-embedded or their alloy-embedded carbon structures for photocatalysis or other energy-related applications.

Keyword:

Cocatalyst Hydrogen evolution reaction Nanoconfined assembly Photocatalysis Solar hydrogen

Community:

  • [ 1 ] [Li, Jie]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Lu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Li, Jiawei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [An, Ping]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Hou, Yidong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Zhang, Jinshui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 张金水

    [Zhang, Jinshui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, 2 Xueyuan Rd, Fuzhou 350108, Fujian, Peoples R China

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Source :

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

ISSN: 2168-0485

Year: 2019

Issue: 16

Volume: 7

Page: 14023-14030

7 . 6 3 2

JCR@2019

7 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 25

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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