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Abstract:
Crystalline carbon nitride (CCN)-based semiconductors have recently attracted widespread attention in solar energy conversion. However, further modifying the photocatalytic ability of CCN always results in a trade-off between high crystallinity and good photocatalytic performance. Herein, a facile defect engineering strategy was demonstrated to modify the CCN photocatalysts. Results confirmed that the obtained D-CCN maintained the high crystallinity; additionally, the hydrogen production rate of D-CCN was approximately 8 times higher than that of CCN. Particularly, it could produce H-2 even if the incident light wavelength extended to 610 nm. The significantly improved photocatalytic activity could be ascribed to the introduction of defects into the CCN polymer network to form the midgap states, which significantly broadened the visible-light absorption range and accelerated the charge separation for photoredox catalysis.
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CHEMSUSCHEM
ISSN: 1864-5631
Year: 2019
Issue: 14
Volume: 12
Page: 3257-3262
7 . 9 6 2
JCR@2019
7 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 114
SCOPUS Cited Count: 114
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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