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author:

Ren, Wei (Ren, Wei.) [1] | Cheng, Jiajia (Cheng, Jiajia.) [2] (Scholars:成佳佳) | Ou, Honghui (Ou, Honghui.) [3] | Huang, Caijin (Huang, Caijin.) [4] (Scholars:黄彩进) | Titirici, Maria-Magdalena (Titirici, Maria-Magdalena.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] (Scholars:王心晨)

Indexed by:

EI Scopus SCIE

Abstract:

Crystalline carbon nitride (CCN)-based semiconductors have recently attracted widespread attention in solar energy conversion. However, further modifying the photocatalytic ability of CCN always results in a trade-off between high crystallinity and good photocatalytic performance. Herein, a facile defect engineering strategy was demonstrated to modify the CCN photocatalysts. Results confirmed that the obtained D-CCN maintained the high crystallinity; additionally, the hydrogen production rate of D-CCN was approximately 8 times higher than that of CCN. Particularly, it could produce H-2 even if the incident light wavelength extended to 610 nm. The significantly improved photocatalytic activity could be ascribed to the introduction of defects into the CCN polymer network to form the midgap states, which significantly broadened the visible-light absorption range and accelerated the charge separation for photoredox catalysis.

Keyword:

conjugated polymer crystalline carbon nitride defect engineering hydrogen evolution photocatalysis

Community:

  • [ 1 ] [Ren, Wei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Cheng, Jiajia]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Ou, Honghui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Huang, Caijin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Titirici, Maria-Magdalena]Queen Mary Univ London, Sch Engn & Mat Sci, London E1 4NS, England
  • [ 7 ] [Titirici, Maria-Magdalena]Imperial Coll London, Dept Chem Engn, South Kensington Campus, London SE7 2AZ, England

Reprint 's Address:

  • 成佳佳 王心晨

    [Cheng, Jiajia]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China;;[Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China

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Related Keywords:

Source :

CHEMSUSCHEM

ISSN: 1864-5631

Year: 2019

Issue: 14

Volume: 12

Page: 3257-3262

7 . 9 6 2

JCR@2019

7 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 114

SCOPUS Cited Count: 114

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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