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Abstract:
Heterogeneous photocatalysis is a promising strategy for addressing the worldwide environmental pollution and energy shortage issues. However, unlike TiO2 with good photostability, the intrinsic drawback of photoinduced decomposition, i.e., photocorrosion, of semiconductors significantly challenges durable photocatalysis. In this review, the photocorrosion mechanisms of typical semiconductors and different characterization methods proposed for monitoring the photocorrosion process of semiconductor-based composite photocatalysts are elaborated. Dedicated emphasis is put on the strategies for improving the anti-photocorrosion property of semiconductor-based photocatalysts, including modifying the crystal structure or morphology of semiconductors, doping with heteroatoms, hybridizing with various semiconductors and/or cocatalysts, and regulating the photocatalytic reaction conditions. Finally, we cast a personal prospect on the future development of the rational design of corrosion-controlled semiconductor-based photocatalysts toward versatile photoredox applications.
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ACS CATALYSIS
ISSN: 2155-5435
Year: 2019
Issue: 5
Volume: 9
Page: 4642-4687
1 2 . 3 5
JCR@2019
1 1 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 27 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
Affiliated Colleges: