Indexed by:
Abstract:
BACKGROUD Organic contaminants in secondary reverse osmosis (SRO) concentrate pose a severe threat to the ecosystem, due to their potential toxicity. In this study, potential of coagulation/granular activated carbon (GAC) adsorption combined with UV/H2O2 and ozonation for removing organic matter from industrial secondary RO concentrate was systematically investigated. RESULTS Coagulation with 2.0 mmol L-1 FeCl3 yielded 40% removal of dissolved organic carbon (DOC), while adsorption with 5 g L-1 GAC could boost the removal efficiency up to 78.2%. Fractionation results showed that both coagulation and GAC adsorption favored hydrophobic organics. UV/H2O2 oxidation was capable of removing 87.4% of DOC, which outperformed ozonation (58.2%). UV/H2O2 and ozonation showed similar behavior in dissolved organic matter (DOM) degradation: a portion of hydrophobic organics were first transformed into hydrophilic fractions prior to final mineralization. Conclusion Coupling of GAC as post-treatment with a UV/H2O2 process yielded 97.9% removal of DOC and the corresponding electrical energy per order (EE/O) was decreased from 66.7 to 35.8 kWh m(-3). Consequently, a simple UV/H2O2 and GAC hybrid process was proposed to be a suitable method for removing DOM from SRO concentrate. (c) 2018 Society of Chemical Industry
Keyword:
Reprint 's Address:
Email:
Version:
Source :
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
ISSN: 0268-2575
Year: 2019
Issue: 4
Volume: 94
Page: 1091-1099
2 . 7 5
JCR@2019
2 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 9
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: