The　development　of　bimetallic　transition-metal　sulfide　and　nitrogen-doped　carbon　composites　with　unique　hollow　structure　is　highly　desirable　for　energy　storage　applications　but　is　also　challenging.　In　the　present　work,　we　demonstrate　a　facile　metal　organic　framework　engaged　strategy　for　synthesizing　bimetallic　nickel　cobalt　sulfide　and　nitrogen-doped　carbon　composites　with　hollow　spherical　structure　(denoted　as　hollow　Ni-Co-S-n/NC　composites)　and　a　Ni/Co　molar　ratio　(n　value)　that　can　be　easily　controlled.　When　evaluated　as　electrode　materials　for　both　supercapacitors　and　lithium　ion　batteries,　it　is　found　that　the　hollow　Ni-Co-S-0.5/NC　composite　with　a　Ni/Co　molar　ratio　of　0.5　exhibits　optimal　electrochemical　performance.　The　hollow　Ni-Co-S-0.5/NC　composite　exhibits　a　high　specific　capacity　of　543.9　C　g(-1)　at　1　A　g(-1)　and　maintains　a　capacity　retention　of　67.3%　when　the　current　density　is　increased　to　20　A　g(-1).　An　asymmetric　supercapacitor　based　on　the　hollow　Ni-Co-S-0.5/NC　composite　is　fabricated,　which　shows　good　electrochemical　performance　with　a　high　energy　density　of　39.6　W　h　kg(-1)　at　a　power　density　of　808　W　kg(-1).　For　lithium　storage,　the　hollow　Ni-1Co-1S-0.5/NC　composite　manifests　a　high　reversible　discharge　capacity　of　755.0　mA　h　g(-1)　at　200　mA　g(-1)　for　200　cycles　as　well　as　good　rate　capability.　The　excellent　electrochemical　performance　could　be　attributed　to　the　desirable　structural,　compositional,　and　component　advantages.　This　work　could　offer　new　insight　into　the　rational　design　and　synthesis　of　highly　efficient　electrode　materials　for　both　supercapacitors　and　lithium　ion　batteries.