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Abstract：
Two hexameric chromium-lanthanide heterometallic cluster substituted polyoxometalates (POMs), K9Na14Cs12H[Cr6Dy6(H2O)(12)(alpha-GeW10O38)(6)]center dot 33H(2)O (1-Dy) and K9Na14Cs12H[Cr6Tb6(H2O)(12)(alpha-GeW10O38)(6)]center dot 65H(2)O (1-Tb), have been hydrothermally synthesized and structurally characterized through single-crystal X-ray diffraction analysis, powder X-ray diffraction analysis, thermogravimetric analysis, infrared spectroscopy and solid-state ultraviolet-visible spectroscopy. Compounds 1-Dy and 1-Tb represent the first examples of 3d-4f heterometallic cluster substituted POMs incorporating chromium-lanthanide clusters. What＇s more, magnetic investigations indicate that overall antiferromagnetic coupling is present in 1-Dy and 1-Tb.
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NEW JOURNAL OF CHEMISTRY
ISSN： 1144-0546
Year： 2019
Issue： 7
Volume： 43
Page： 3011-3016
3 . 2 8 8
JCR@2019
2 . 7 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：184
JCR Journal Grade：2
CAS Journal Grade：3
Cited Count：
WoS CC Cited Count： 12
SCOPUS Cited Count： 11
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 1
Affiliated Colleges：
