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author:

Wang, Congyong (Wang, Congyong.) [1] | Lin, Hang (Lin, Hang.) [2] | Xiang, Xiaoqiang (Xiang, Xiaoqiang.) [3] | Cheng, Yao (Cheng, Yao.) [4] | Huang, Qingming (Huang, Qingming.) [5] (Scholars:黄清明) | Gao, Yan (Gao, Yan.) [6] | Cui, Xiangshui (Cui, Xiangshui.) [7] | Wang, Yuansheng (Wang, Yuansheng.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Despite possessing admirable features for optical thermometry, a semiconductor (SC) nanocrystal based material has the innate shortcomings of poor stability towards environmental variation, complicated/unfriendly preparation procedures, low production, and the necessity of a delicate structural design to achieve dual-emission. To well address these issues, a kind of dual-phase devitrified glass (DG) strategy is proposed. In the case of dual-phase DG embedded with CsPbBr3 SC and EuPO4, fabricated via a glass self-crystallization route, it has been found that the spatial isolation of two emitting species enables non-interfering luminescence with different temperature-responsive behaviors. Utilizing the fluorescence intensity ratio (FIR) between the Eu3+: 4f -> 4f emission from EuPO4 and the exciton emission from CsPbBr3, a self-calibrating thermometer with ultra-high sensitivity (S-a = 0.082 K-1 and S-r = 1.80% K-1, 303-483 K) is achieved. Importantly, the introduction of a CsPbBr3 perovskite SC into the inert glass matrix greatly improves its thermal stability, and so highly repeatable thermometry in the dual-phase DG is achieved (97.12% for 10 heating-cooling cycles). This work demonstrates an effective pathway for accurate, reliable and robust thermometry by integrating SC nanocrystals and rare-earth-ions into an inorganic glassy composite.

Keyword:

Community:

  • [ 1 ] [Wang, Congyong]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Xiang, Xiaoqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Cheng, Yao]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Gao, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Cui, Xiangshui]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Wang, Congyong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Xiang, Xiaoqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Cheng, Yao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Gao, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Cui, Xiangshui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 14 ] [Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 15 ] [Wang, Congyong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 16 ] [Xiang, Xiaoqiang]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 17 ] [Gao, Yan]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 18 ] [Cui, Xiangshui]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 19 ] [Lin, Hang]State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 20 ] [Huang, Qingming]Fuzhou Univ, Instrumentat Anal & Res Ctr, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China;;[Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China;;[Lin, Hang]State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

Year: 2018

Issue: 37

Volume: 6

Page: 9964-9971

6 . 6 4 1

JCR@2018

5 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 65

SCOPUS Cited Count: 75

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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