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Despite possessing admirable features for optical thermometry, a semiconductor (SC) nanocrystal based material has the innate shortcomings of poor stability towards environmental variation, complicated/unfriendly preparation procedures, low production, and the necessity of a delicate structural design to achieve dual-emission. To well address these issues, a kind of dual-phase devitrified glass (DG) strategy is proposed. In the case of dual-phase DG embedded with CsPbBr3 SC and EuPO4, fabricated via a glass self-crystallization route, it has been found that the spatial isolation of two emitting species enables non-interfering luminescence with different temperature-responsive behaviors. Utilizing the fluorescence intensity ratio (FIR) between the Eu3+: 4f -> 4f emission from EuPO4 and the exciton emission from CsPbBr3, a self-calibrating thermometer with ultra-high sensitivity (S-a = 0.082 K-1 and S-r = 1.80% K-1, 303-483 K) is achieved. Importantly, the introduction of a CsPbBr3 perovskite SC into the inert glass matrix greatly improves its thermal stability, and so highly repeatable thermometry in the dual-phase DG is achieved (97.12% for 10 heating-cooling cycles). This work demonstrates an effective pathway for accurate, reliable and robust thermometry by integrating SC nanocrystals and rare-earth-ions into an inorganic glassy composite.
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JOURNAL OF MATERIALS CHEMISTRY C
ISSN: 2050-7526
Year: 2018
Issue: 37
Volume: 6
Page: 9964-9971
6 . 6 4 1
JCR@2018
5 . 7 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:284
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 65
SCOPUS Cited Count: 75
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: