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author:

Huang, Kuan (Huang, Kuan.) [1] | Zhang, Jia-Yin (Zhang, Jia-Yin.) [2] | Liu, Fujian (Liu, Fujian.) [3] (Scholars:刘福建) | Dai, Sheng (Dai, Sheng.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Because CO2 is the main greenhouse gas, its capture and catalytic conversion are thought to be significant issues to be solved at the current time. Given the thermodynamically stable and inert nature of CO2, it is highly desirable to develop advanced catalysts to facilitate the transformation of CO2 to other high-value-added chemicals under mild conditions. Within this regard, porous organic polymers (POPS), featuring large surface areas, high thermal stabilities, diverse building blocks, and tunable porous structures, are an ideal platform for the construction of heterogeneous catalysts for CO2 conversion. Incorporating active sites that are capable of activating CO2 and/or substrates into the frameworks of POPs can facilitate CO2 conversion. In this Review, the most recent advances in the design and synthesis of POP-based heterogeneous catalysts for the conversion of CO2 are summarized. We mainly focus on the synthetic strategies researchers have used for incorporating active sites into POP frameworks to prepare heterogeneous catalysts for CO2 conversion, including N-doping, metalation, and ionic functionalization. Problems remaining to be addressed in this field are analyzed, and future directions are outlined.

Keyword:

CO2 conversion greenhouse gas heterogeneous catalysis porous organic polymers reusability

Community:

  • [ 1 ] [Huang, Kuan]Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Sch Resources Environm & Chem Engn, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China
  • [ 2 ] [Zhang, Jia-Yin]Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Sch Resources Environm & Chem Engn, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China
  • [ 3 ] [Liu, Fujian]Fuzhou Univ, NERC CFC, Sch Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Dai, Sheng]Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
  • [ 5 ] [Dai, Sheng]Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA

Reprint 's Address:

  • 刘福建

    [Huang, Kuan]Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Sch Resources Environm & Chem Engn, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China;;[Liu, Fujian]Fuzhou Univ, NERC CFC, Sch Chem Engn, Fuzhou 350116, Fujian, Peoples R China

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Source :

ACS CATALYSIS

ISSN: 2155-5435

Year: 2018

Issue: 10

Volume: 8

Page: 9079-9102

1 2 . 2 2 1

JCR@2018

1 1 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 189

SCOPUS Cited Count: 198

ESI Highly Cited Papers on the List: 5 Unfold All

  • 2023-3
  • 2023-1
  • 2022-11
  • 2022-9
  • 2022-7

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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