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author:

Bian, Huiyang (Bian, Huiyang.) [1] | Wei, Liqing (Wei, Liqing.) [2] | Lin, Chunxiang (Lin, Chunxiang.) [3] (Scholars:林春香) | Ma, Qianli (Ma, Qianli.) [4] | Dai, Hongqi (Dai, Hongqi.) [5] | Zhu, J. Y. (Zhu, J. Y..) [6]

Indexed by:

SCIE

Abstract:

Two lignin-containing cellulose nanofibril (LCNF) samples, produced from two unbleached kraft pulps with very different lignin contents, were used to produce reinforced polyvinyl alcohol (PVA) hydrogels. The effects of LCNF loading (0.25-2 wt %) and lignin content on the rheological and mechanical properties of the reinforced hydrogels were investigated. The 2 wt % LCNF-reinforced PVA hydrogels exhibited up to a 17-fold increase in storage modulus and a 4-fold increase in specific Young's modulus over that of pure PVA hydrogel. Both the mechanical and rheological properties of LCNF-reinforced PVA hydrogels can be tuned by varying LCNF loading and LCNF lignin content. During LCNF production, lignin reduced cellulose depolymerization, resulting in LCNF with high aspect ratios that promoted entanglement and physical bridging of the hydrogel network. Free lignin particles generated during LCNF production acted as multifunctional nanospacers that increased porosity of the hydrogels. Because LCNFs were produced from unbleached chemical pulps, which have high yields and do not require bleaching, this study provides a more sustainable approach to utilize lignocelluloses to produce biomass-based hydrogels than by methods using commercial bleached pulps.

Keyword:

Hydrogel Lignin containing cellulose nanofibrils (LCNFs) Polyvinyl alcohol (PVA) Rheological and mechanical properties

Community:

  • [ 1 ] [Bian, Huiyang]Nanjing Forestry Univ, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Jiangsu, Peoples R China
  • [ 2 ] [Dai, Hongqi]Nanjing Forestry Univ, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Jiangsu, Peoples R China
  • [ 3 ] [Bian, Huiyang]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
  • [ 4 ] [Wei, Liqing]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
  • [ 5 ] [Lin, Chunxiang]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
  • [ 6 ] [Ma, Qianli]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
  • [ 7 ] [Zhu, J. Y.]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
  • [ 8 ] [Lin, Chunxiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Ma, Qianli]South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China

Reprint 's Address:

  • [Zhu, J. Y.]US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA

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Source :

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

ISSN: 2168-0485

Year: 2018

Issue: 4

Volume: 6

Page: 4821-4828

6 . 9 7

JCR@2018

7 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 156

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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