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author:

Yang, Tangtao (Yang, Tangtao.) [1] | Peng, Junmin (Peng, Junmin.) [2] | Zheng, Yun (Zheng, Yun.) [3] | He, Xuan (He, Xuan.) [4] | Hou, Yidong (Hou, Yidong.) [5] (Scholars:侯乙东) | Wu, Ling (Wu, Ling.) [6] (Scholars:吴棱) | Fu, Xianzhi (Fu, Xianzhi.) [7] (Scholars:付贤智)

Indexed by:

EI Scopus SCIE

Abstract:

Advanced oxidation processes (AOPs) for wastewater treatment have attracted much attention for their efficient capability in destroying persistent and toxic organic compounds. In this study, we reported a simple impregnation-calcination method to fabricate ZnO modified TiO2 (Zn-TiO2) nanocomposites and employed them as catalysts for degradation of organic pollutants in water. The results show that 7at%Zn-TiO2 exhibits much better performances of photocatalysis, catalytic ozonation and photocatalytic ozonation than pure TiO2, which could be due to its richer surface hydroxyl groups and higher separation efficiency of photogenerated electron-hole pairs. The total organic carbon (TOC) removal efficiency of salicylic acid (SA) in UV/O-3/7at%Zn-TiO2 is higher than the sum of those in UV/7at%Zn-TiO2 and O-3 processes, indicative of a synergistic effect between photo catalysis and ozonation. Mechanism studies demonstrate that the active species such as H2O2, h(+), center dot OH, center dot O-2(-) and O-1(2) are responsible for SA degradation. Meanwhile, the intermediates of SA mineralization were identified by HPLC-MS and its mineralization pathway was proposed. Reusability test verifies a high stability of 7at%ZnTiO2 in the photocatalytic ozonation process, and the catalyst can be applied in a wide pH range of aqueous solution from 3.5 to 10.0. This work puts forward a new application of the easily available Zn-TiO2 nano composites and might drive the advance of photocatalytic ozonation approach for water purification.

Keyword:

Photocatalytic ozonation Synergistic effect TiO2 Water purification

Community:

  • [ 1 ] [Yang, Tangtao]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Peng, Junmin]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zheng, Yun]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [He, Xuan]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Hou, Yidong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Wu, Ling]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Fu, Xianzhi]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 侯乙东

    [Hou, Yidong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

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Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2018

Volume: 221

Page: 223-234

1 4 . 2 2 9

JCR@2018

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 217

SCOPUS Cited Count: 225

ESI Highly Cited Papers on the List: 31 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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