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The phosphorus (P) modified MoO3-Bi2SiO5/SiO2 catalyst was prepared by a simple co-impregnation method and investigated in the epoxidation of propylene by molecular oxygen. The catalyst was characterized by X-ray diffraction (XRD), N-2 adsorption-desorption analysis, NH3-temperature-programmed desorption (NH3-TPD), transmission electron microscopy, and Raman spectroscopy. It was found that the P-modified MoO3-Bi2SiO5/SiO2 catalyst with a P/Mo molar ratio of 0.5 exhibits the best catalytic performance for epoxidation of propylene by O-2, the TOFs for propylene oxide (PO) formation was four times higher than that of the unmodified one at 633 K. The modification by P could promote the dispersion of MoO3 nanoparticles and increase the number of weak and moderate acid sites with respect to the phosphorus-free MoO3-Bi2SiO5/SiO2 catalyst, which were beneficial to the formation of PO. Moreover, the introduction of P also could protect the mesoporous structure by inhibiting the formation of Bi2Mo3O12, which was beneficial to the dispersion of active species. We suppose that the phosphorus, bismuth and molybdenum species of P-modified MoO3-Bi2SiO5/SiO2 catalyst play important roles for propylene epoxidation by molecular oxygen.
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RESEARCH ON CHEMICAL INTERMEDIATES
ISSN: 0922-6168
Year: 2017
Issue: 12
Volume: 43
Page: 7055-7071
1 . 6 7 4
JCR@2017
2 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:226
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4