• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Xu, Shengqiang (Xu, Shengqiang.) [1] | Huang, Qingming (Huang, Qingming.) [2] (Scholars:黄清明) | Xu, Yanting (Xu, Yanting.) [3] | Ye, Zhuoliang (Ye, Zhuoliang.) [4] | Chen, Xiaohui (Chen, Xiaohui.) [5] (Scholars:陈晓晖)

Indexed by:

EI Scopus SCIE

Abstract:

The phosphorus (P) modified MoO3-Bi2SiO5/SiO2 catalyst was prepared by a simple co-impregnation method and investigated in the epoxidation of propylene by molecular oxygen. The catalyst was characterized by X-ray diffraction (XRD), N-2 adsorption-desorption analysis, NH3-temperature-programmed desorption (NH3-TPD), transmission electron microscopy, and Raman spectroscopy. It was found that the P-modified MoO3-Bi2SiO5/SiO2 catalyst with a P/Mo molar ratio of 0.5 exhibits the best catalytic performance for epoxidation of propylene by O-2, the TOFs for propylene oxide (PO) formation was four times higher than that of the unmodified one at 633 K. The modification by P could promote the dispersion of MoO3 nanoparticles and increase the number of weak and moderate acid sites with respect to the phosphorus-free MoO3-Bi2SiO5/SiO2 catalyst, which were beneficial to the formation of PO. Moreover, the introduction of P also could protect the mesoporous structure by inhibiting the formation of Bi2Mo3O12, which was beneficial to the dispersion of active species. We suppose that the phosphorus, bismuth and molybdenum species of P-modified MoO3-Bi2SiO5/SiO2 catalyst play important roles for propylene epoxidation by molecular oxygen.

Keyword:

Molybdenum Phosphorus Propylene epoxidation Propylene oxide Supported catalyst

Community:

  • [ 1 ] [Xu, Shengqiang]Fuzhou Univ, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Xu, Yanting]Fuzhou Univ, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Ye, Zhuoliang]Fuzhou Univ, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen, Xiaohui]Fuzhou Univ, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Xu, Shengqiang]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Xu, Yanting]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Chen, Xiaohui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Huang, Qingming]Fuzhou Univ, Testing Ctr, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 陈晓晖

    [Chen, Xiaohui]Fuzhou Univ, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China;;[Chen, Xiaohui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

Show more details

Related Keywords:

Source :

RESEARCH ON CHEMICAL INTERMEDIATES

ISSN: 0922-6168

Year: 2017

Issue: 12

Volume: 43

Page: 7055-7071

1 . 6 7 4

JCR@2017

2 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:226

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Online/Total:119/10011901
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1