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Abstract:
Two nanostructured electrode materials are fabricated and used to construct cost-effective asymmetric supercapacitors (ASCs). Hierarchical nickel cobalt oxide nanoarrays (NCO-NA) consisting of nanosheets (NCO-NS) or nanowires (NCO-NW) are uniformly grown on Ni foam by a simple, effective, and generally applicable method, while biowaste-derived hierarchical porous carbon (Bio-HPC) with an interconnected microstructure is fabricated by pretreatment with potassium hydroxide and followed by direct pyrolysis. Considering the mass of NiCo2O4, the maximum specific capacitance of the hierarchical NCO-NS and NCO-NW electrodes are 2300 and 2333 F g(-1) respectively, and the specific capacitance of the Bio-HPC electrode is 253.9 F g(-1) at a scan rate of 5 mV s(-1). NCO-NA, Bio-HPC, a piece of polypropylene membrane, and 30 wt % KOH solution are assembled into a high-performance, low-cost ASC with the capability of rapidly storing electrical energy. The NCO-NW//Bio-HPC ASC exhibits a higher energy density compared with NCO-NS//Bio-HPC ASC, while the latter shows better cycling performance (the capacitance still remains 91.12% after 2000 cycles).
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ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN: 2168-0485
Year: 2017
Issue: 11
Volume: 5
Page: 9903-9913
6 . 1 4
JCR@2017
7 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:226
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 31
SCOPUS Cited Count: 30
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: