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Abstract：
In the drive toward green and sustainable chemistry, exploring efficient and stable metal-free photocatalysts with broadband solar absorption from the UV to near-infrared region for the photoreduction of water to H-2 remains a big challenge. To this end, a binary nanohybrid (BP/CN) of two-dimensional (2D) black phosphorus (BP) and graphitic carbon nitride (CN) was designed and used as a metal-free photocatalyst for the first time. During irradiation of BP/CN in water with ＞420 and ＞780 nm light, solid H-2 gas was generated, respectively. Owing to the interfacial interaction between BP and CN, efficient charge transfer occurred, thereby enhancing the photocatalytic performance. The efficient charge-trapping and transfer processes were thoroughly investigated with time-resolved diffuse reflectance spectroscopic measurement. The present results show that BP/CN is a metal-free photocatalyst for artificial photosynthesis and renewable energy conversion.
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN： 0002-7863
Year： 2017
Issue： 37
Volume： 139
Page： 13234-13242
1 4 . 3 5 7
JCR@2017
1 4 . 5 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：226
JCR Journal Grade：1
CAS Journal Grade：1
Cited Count：
WoS CC Cited Count： 895
SCOPUS Cited Count： 917
ESI Highly Cited Papers on the List： 36 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 0
Affiliated Colleges：
