Enantioselective conjugate addition of hydroxylamines to alpha,beta-unsaturated 2-acyl imidazoles catalyzed by a chiral-at-metal Rh(III) complex - Details

author：

Deng, Tao (Deng, Tao.) ^[1] | Thota, Ganesh Kumar (Thota, Ganesh Kumar.) ^[2] | Li, Yi (Li, Yi.) ^[3] (Scholars：李毅) | Kang, Qiang (Kang, Qiang.) ^[4]

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EI Scopus SCIE

Abstract：

A　catalytic　enantioselective　hydroxyamination　of　alpha,beta-unsaturated　2-acyl　imidazoles　with　N-protected　hydroxyl　amines　catalyzed　by　a　chiral-at-metal　Rh(III)　complex　(0.5-2　mol%)　has　been　developed.　The　approach　affords　valuable　N-Boc　protected　beta-amino　acid　derivatives　in　moderate　to　good　yields　with　high　enantioselectivity　(up　to　94%　yield,　99.5%　ee).

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[ 1 ] [Deng, Tao]Fuzhou Univ, Dept Chem, Fuzhou 350116, Peoples R China
[ 2 ] [Li, Yi]Fuzhou Univ, Dept Chem, Fuzhou 350116, Peoples R China
[ 3 ] [Thota, Ganesh Kumar]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, 155 Yangqiao Rd West, Fuzhou 350002, Peoples R China
[ 4 ] [Kang, Qiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, 155 Yangqiao Rd West, Fuzhou 350002, Peoples R China

Reprint 's Address：

[Kang, Qiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, 155 Yangqiao Rd West, Fuzhou 350002, Peoples R China

Email：

kangq@fjirsm.ac.cn

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Enantioselective conjugate addition of hydroxylamines to α,β-unsaturated 2-acyl imidazoles catalyzed by a chiral-at-metal Rh(III) complex
2017，Organic Chemistry Frontiers
Enantioselective conjugate addition of hydroxylamines to α,β-unsaturated 2-acyl imidazoles catalyzed by a chiral-at-metal Rh(III) complex
2017，Organic Chemistry Frontiers

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ORGANIC CHEMISTRY FRONTIERS

ISSN： 2052-4129

Year： 2017

Issue： 4

Volume： 4

Page： 573-577

5 . 4 5 5

JCR@2017

4 . 6 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：226

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count： 26

SCOPUS Cited Count： 27

ESI Highly Cited Papers on the List： 3 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

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