• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Moon, Gun-hee (Moon, Gun-hee.) [1] | Fujitsuka, Mamoru (Fujitsuka, Mamoru.) [2] | Kim, Sooyeon (Kim, Sooyeon.) [3] | Majima, Tetsuro (Majima, Tetsuro.) [4] | Wang, Xinchen (Wang, Xinchen.) [5] (Scholars:王心晨) | Choi, Wonyong (Choi, Wonyong.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

We report that in situ incorporation of both potassium and phosphate species into a polymeric carbon nitride (CN) framework highly enhanced the photo production of hydrogen peroxide (H2O2) without the use of any noble-metal cocatalysts. The incorporation of earth-abundant heteroelements (K, P, and O) (i) introduced the negative surface charge over the entire pH range through surface functionalization by phosphate species, (ii) increased the lifetime of the transient species to a picosecond time scale via the formation of charge separation states, (iii) facilitated the interfacial electron transfer to dioxygen, and (iv) inhibited the decomposition of in situ generated H2O2. As a result, the modified CN showed apparent quantum yields (P, for H2O2 production) that are enhanced by about 25 and 17 times (Phi(420) = 8.0%; Phi(320) = 26.2%) from those of bare CN (Phi(420) = 0.32%; Phi(320) = 1.55%) under monochromatic irradiation of 420 and 320 nm, respectively. This study clearly demonstrated a simple way to design multiple heteroelement-incorporated CN compounds that consist of earth-abundant elements only (C, N, K, P, O) for the development of practical and economical solar conversion photocatalytic materials.

Keyword:

carbon nitride hydrogen peroxide synthesis photocatalysis proton coupled electron transfer (PCET) solar fuel

Community:

  • [ 1 ] [Moon, Gun-hee]Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 37673, South Korea
  • [ 2 ] [Choi, Wonyong]Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 37673, South Korea
  • [ 3 ] [Moon, Gun-hee]Pohang Univ Sci & Technol POSTECH, Div Environm Sci & Engn, Pohang 37673, South Korea
  • [ 4 ] [Choi, Wonyong]Pohang Univ Sci & Technol POSTECH, Div Environm Sci & Engn, Pohang 37673, South Korea
  • [ 5 ] [Fujitsuka, Mamoru]Osaka Univ, Inst Sci & Ind Res SANKEN, Osaka 5670047, Japan
  • [ 6 ] [Kim, Sooyeon]Osaka Univ, Inst Sci & Ind Res SANKEN, Osaka 5670047, Japan
  • [ 7 ] [Majima, Tetsuro]Osaka Univ, Inst Sci & Ind Res SANKEN, Osaka 5670047, Japan
  • [ 8 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Choi, Wonyong]Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 37673, South Korea;;[Choi, Wonyong]Pohang Univ Sci & Technol POSTECH, Div Environm Sci & Engn, Pohang 37673, South Korea

Show more details

Related Keywords:

Source :

ACS CATALYSIS

ISSN: 2155-5435

Year: 2017

Issue: 4

Volume: 7

Page: 2886-2895

1 1 . 3 8 4

JCR@2017

1 1 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 287

SCOPUS Cited Count: 294

ESI Highly Cited Papers on the List: 19 Unfold All

  • 2025-1
  • 2024-11
  • 2024-9
  • 2024-7
  • 2024-5
  • 2024-3
  • 2024-1
  • 2023-11
  • 2023-9
  • 2023-5
  • 2023-3
  • 2023-1
  • 2022-11
  • 2022-9
  • 2022-7
  • 2022-5
  • 2022-3
  • 2022-1
  • 2021-7

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:101/10052682
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1