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Four new metal-free organic dyes QX15-18 based on indeno[1,2-b]indole have been successfully designed and synthesized. These D pi A type dyes consist of an indeno[1,2-b]indole donor and a benzene or thiophene pi-bridge. In an attempt to tune their photoelectric properties, the effects of different acceptor groups including cyanoacrylic acid, rhodanine-3-acetic acid, and 2-(1,1dicyanomethylene)rhodanine (DCRD) have been investigated. The dye QX15 with a cyanoacrylic acid acceptor exhibited a highest V-OC of 813 mV and a high J(sc) of 11.0 mA cm (-2), generating a highest power conversion efficiency of 6.29%. Meanwhile, the dye QX18 with a DCRD acceptor and a thiophene pi-bridge showed a significantly improved J(sc) of 11.9 mA cm(-2), which could be attributed to its red-shifted absorption spectra and high molar absorption coefficient. (C) 2016 Elsevier Ltd. All rights reserved.
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DYES AND PIGMENTS
ISSN: 0143-7208
Year: 2017
Volume: 139
Page: 274-282
3 . 7 6 7
JCR@2017
4 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:226
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 24
SCOPUS Cited Count: 26
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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