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Abstract：
The search for metal-free organic photocatalysts for H-2 production from water using visible light remains a key challenge. Reported herein is a molecular structural design of pure organic photocatalysts, derived from conjugated polybenzothiadiazoles, for photocatalytic H-2 evolution using visible light. By alternating the substitution position of the electron-withdrawing benzothiadizole unit on the phenyl unit as a comonomer, various polymers with either one-or threedimensional structures were synthesized and the effect of the molecular structure on their catalytic activity was investigated. Photocatalytic H-2 evolution efficiencies up to 116 mu mol h(-1) were observed by employing the linear polymer based on a phenyl-benzothiadiazole alternating main chain, with an apparent quantum yield (AQY) of 4.01% at 420 nm using triethanolamine as the sacrificial agent.
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Source ：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN： 1433-7851
Year： 2016
Issue： 32
Volume： 55
Page： 9202-9206
1 1 . 9 9 4
JCR@2016
1 6 . 1 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：235
JCR Journal Grade：1
CAS Journal Grade：1
Cited Count：
WoS CC Cited Count： 343
SCOPUS Cited Count： 351
ESI Highly Cited Papers on the List： 37 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 0
Affiliated Colleges：
