A polyhedron-based cobalt-organic framework for gas adsorption and separation - Details

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Abstract：

A　cobalt-organic　framework　(1)　consisted　of　close-packed　polyhedral　cages　is　isostructural　to　CPM-35-Ni.　The　activated　sample　(la)　can　adsorb　high　H-2　uptake　of　88.3　cm(3)　g(-1)　(0.79　wt.%)　at　77　K　and　1.0　bar.　Remarkably,　la　shows　high　CO2　adsorption　capacity　and　good　adsorption　selectivity　for　CO2　over　CH4　and　N-2.　(C)　2016　Elsevier　B.V.　All　rights　reserved.

Keyword：

CO2/CH4 and CO2/N-2 selectivity H-2 and CO2 uptakes MOF Polyhedron cages

Community：

[ 1 ] [Zhang, Lei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
[ 2 ] [Chen, Wen-Zhe]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
[ 3 ] [Zhang, Lei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[ 4 ] [Yang, Wenbin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[ 5 ] [Wu, Xiao-Yuan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[ 6 ] [Huo, Miao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[ 7 ] [Lu, Can-Zhong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[ 8 ] [Chen, Wen-Zhe]Xiamen Univ Technol, Xiamen 361024, Fujian, Peoples R China

Reprint 's Address：

陈文哲
[Chen, Wen-Zhe]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China;;[Lu, Can-Zhong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Chen, Wen-Zhe]Xiamen Univ Technol, Xiamen 361024, Fujian, Peoples R China

Email：

czlu@fjirsm.ac.cn |
chenwz@fzu.edu.cn

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