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author:

Liu, Yuhan (Liu, Yuhan.) [1] | Wei, Lin (Wei, Lin.) [2] | Hu, Yizhen (Hu, Yizhen.) [3] | Huang, Xiangyue (Huang, Xiangyue.) [4] | Wang, Jiaqi (Wang, Jiaqi.) [5] | Li, Junqian (Li, Junqian.) [6] | Hu, Xiaolin (Hu, Xiaolin.) [7] (Scholars:胡晓琳) | Zhuang, Naifeng (Zhuang, Naifeng.) [8] (Scholars:庄乃锋)

Indexed by:

EI Scopus SCIE

Abstract:

Graphene nanoribbons decorated with noble metal nanoparticles possess great catalytic performance for ethanol oxidation in direct ethanol fuel cells. Herein, PtPd alloy catalysts supported on graphene nanoribbons are researched, and an appropriate Pt-Pd component with the mole ratios of 0.46:0.54 is found to possess excellent catalytic activity and durability. Moreover, the density functional theory analysis shows that the composite catalyst with Pt:Pd ratio of 1:1 owns the highest negative electronic property and the high adsorption energy to restrict CO adsorption. The great CO anti-poisoning ability may be the main reason for the excellent catalytic performance of Pt0.46Pd0.54/GNRs catalyst (C) 2015 Elsevier B.V. All rights reserved.

Keyword:

CO anti-poisoning Density functional theory Electrocatalytic activity Fuel cell PtPd alloy catalyst

Community:

  • [ 1 ] [Liu, Yuhan]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 2 ] [Wei, Lin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 3 ] [Hu, Yizhen]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 4 ] [Huang, Xiangyue]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 5 ] [Wang, Jiaqi]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 6 ] [Li, Junqian]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 7 ] [Hu, Xiaolin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 8 ] [Zhuang, Naifeng]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 胡晓琳

    [Hu, Xiaolin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2016

Volume: 656

Page: 452-457

3 . 1 3 3

JCR@2016

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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