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author:

Han, Chuang (Han, Chuang.) [1] | Chen, Zhang (Chen, Zhang.) [2] | Zhang, Nan (Zhang, Nan.) [3] | Colmenares, Juan Carlos (Colmenares, Juan Carlos.) [4] | Xu, Yi-Jun (Xu, Yi-Jun.) [5] (Scholars:徐艺军)

Indexed by:

EI Scopus SCIE

Abstract:

A simple, low-temperature synthesis approach is reported for planting CdS-sensitized 1D ZnO nanorod arrays on the 2D graphene (GR) sheet to obtain the ternary hierarchical nanostructures, during which graphene oxide (GO) as the precursor of GR acts as a flexible substrate for the formation of ZnO nanorod arrays. The hierarchical CdS-1D ZnO-2D GR hybrids can serve as an efficient visible-light-driven photocatalyst for selective organic transformations. The fast electron transport of 1D ZnO nanorods, the well-known electronic conductivity of 2D GR, the intense visible-light absorption of CdS, the unique hierarchical structure, and the matched energy levels of CdS, ZnO and GR efficiently boost the photogenerated charge carriers separation and transfer across the interfacial domain of hierarchical CdS-1D ZnO-2D GR hybrids under visible light irradiation via three-level electron transfer process. Furthermore, the superior reusability of ternary hybrids is achieved by controlling the reaction parameters, i.e., using visible light irradiation and holes scavenger to prevent ZnO and CdS from photocorrosion. This work demonstrates a facile way of fabricating hierarchical CdS-1D ZnO-2D GR hybrids in a controlled manner and highlights a promising scope of adopting integrative photosensitization and co-catalyst strategy to design more efficient semiconductor-based composite photocatalysts toward solar energy capture and conversion.

Keyword:

cadmium sulfide graphene hierarchical hybrids visible light photocatalysis zinc oxide

Community:

  • [ 1 ] [Han, Chuang]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] [Chen, Zhang]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [Zhang, Nan]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Xu, Yi-Jun]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Han, Chuang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Chen, Zhang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zhang, Nan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 8 ] [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 9 ] [Colmenares, Juan Carlos]Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

Reprint 's Address:

  • [Colmenares, Juan Carlos]Polish Acad Sci, Inst Phys Chem, Ul Kasprzaka 44-52, PL-01224 Warsaw, Poland

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2015

Issue: 2

Volume: 25

Page: 221-229

1 1 . 3 8 2

JCR@2015

1 8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:335

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 399

SCOPUS Cited Count: 402

ESI Highly Cited Papers on the List: 44 Unfold All

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30 Days PV: 1

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