Two　silver(I)　compounds,　[Ag(H(2)mbpz)(Hchda)](n)　(1)　and　[Ag-2(H(2)mbpz)(2)(oba)](n)　(2)　(where　H(2)mbpz=3,3,5,5-tetramethyl-4,4-bipyrazole,　H(2)chda=trans-cyclohexane-dicarboxylic　acid　and　H(2)oba=4,4-oxy-bis-benzoic　acid),　have　been　synthesized　and　characterized　by　single-crystal　X-ray　diffraction　analyses.　In　both　cases,　the　Ag(I)　centers　are　linked　by　H(2)mbpz　ligands　to　form　1-D　Ag(I)-H(2)mbpz　chains;　then,　the　Ag(I)-H(2)mbpz　chains　connect　with　two　neighboring　congeners　through　AgAg　interactions,　forming　2-D　supramolecular　layers.　In　1,　the　dicarboxylate　is　monodeprotonated　and　linked　to　form　an　anion　chain　through　strong　hydrogen　bonding　interaction.　Such　anion　chains　attach　on　two　sides　of　the　supramolecular　layers　via　Ag-O　bonds　to　form　a　neutral　sandwich-like　layered　network.　In　2,　the　dicarboxylate　is　fully　deprotonated　and　adopts　a　(2)-1:1　mode　to　link　two　adjacent　supramolecular　layers　to　form　a　twofold　interpenetrating　3-D　supramolecular　network.　The　thermal　stability　and　luminescence　of　1　were　also　studied.