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Because mercury and ethylenediaminetetreaacetic acid (EDTA) are widely used materials and are commonly found together in the environment due to anthropogenic and industrial releases, there is a great need to develop a bifunctional sensor for both mercury and EDTA. A fluorescent sensor SQ-1 based on a squaraine chromophore with dithiocarbamate (DTC) side arms has been prepared, and its aggregation behavior in aqueous solution has also been investigated. The results show that increasing water concentration in the solution causes dramatic H-aggregation of the symmetric SQ-1 and consequently provides a mercury probe with a visual color change and "turn on" fluorescence via cation induced deaggregation. EDTA, a strong chelator to mercury, accelerates the deaggregation process and enhances the fluorescent emission, which not only improves the sensitivity of SQ-1 to mercury by 10-fold, with a detection limit improvement from 1.1 x 10(-7) M to 1.3 x 10(-8) M, but also provides a way for trace level detection of EDTA, with the detection limit of 8.7 x 10(-8) M. The potential application of this technique for Hg2+ and EDTA determination of river water samples is revealed by proof-of-concept experiments. (C) 2014 Elsevier B.V. All rights reserved.
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SENSORS AND ACTUATORS B-CHEMICAL
ISSN: 0925-4005
Year: 2014
Volume: 203
Page: 435-443
4 . 0 9 7
JCR@2014
8 . 0 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 19
SCOPUS Cited Count: 20
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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