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author:

Wang, Xiuyun (Wang, Xiuyun.) [1] (Scholars:王秀云) | Qi, Xinxin (Qi, Xinxin.) [2] | Chen, Zhilin (Chen, Zhilin.) [3] | Jiang, Lilong (Jiang, Lilong.) [4] (Scholars:江莉龙) | Wang, Ruihu (Wang, Ruihu.) [5] | Wei, Kemei (Wei, Kemei.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

A series of perovskite-type LaCo1-xPtxO3 (x = 0, 0.05, 0.08, and 0.10) were synthesized by the sol-gel method and well characterized by XRD, N-2 physisorption, H-2-TPR, TEM, and XPS. NOx storage and reduction (NSR) performances of LaCo1-xPtxO3 were initially evaluated using NO-to-NO, conversion, NO storage capacity, and NO conversion. The results demonstrate that NSR performances of Pt-substituted perovskites are higher than that of LaCoO3, and LaCo0.92Pt0.08O3 possesses the best NSR properties with NOx conversion of ca. 90% at 350 degrees C. Moreover, LaCo0.92Pt0.08O3 exhibits higher resistance to SO2 poisoning and better regenerability than 1 wt % Pt/16 wt % Ba/Al2O3 in NSR. No obvious deactivation is observed after LaCo0.92Pt0.08O3 has been treated at 850 degrees C for 40 h and subjected to NOx reduction at 350 degrees C for 200 h; the perovskite structure is well maintained in the process. The addition of 10 vol % H2O lowers NO conversion to about 77%, but the removal of water from the reaction gas immediately raises NO conversion to 90%.

Keyword:

Community:

  • [ 1 ] [Wang, Xiuyun]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilize Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Qi, Xinxin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilize Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Jiang, Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilize Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Wei, Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilize Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wang, Xiuyun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Chen, Zhilin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wang, Ruihu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 魏可镁

    [Wei, Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilize Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF PHYSICAL CHEMISTRY C

ISSN: 1932-7447

Year: 2014

Issue: 25

Volume: 118

Page: 13743-13751

4 . 7 7 2

JCR@2014

3 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:268

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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