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Abstract:
A series of perovskite-type LaCo1-xPtxO3 (x = 0, 0.05, 0.08, and 0.10) were synthesized by the sol-gel method and well characterized by XRD, N-2 physisorption, H-2-TPR, TEM, and XPS. NOx storage and reduction (NSR) performances of LaCo1-xPtxO3 were initially evaluated using NO-to-NO, conversion, NO storage capacity, and NO conversion. The results demonstrate that NSR performances of Pt-substituted perovskites are higher than that of LaCoO3, and LaCo0.92Pt0.08O3 possesses the best NSR properties with NOx conversion of ca. 90% at 350 degrees C. Moreover, LaCo0.92Pt0.08O3 exhibits higher resistance to SO2 poisoning and better regenerability than 1 wt % Pt/16 wt % Ba/Al2O3 in NSR. No obvious deactivation is observed after LaCo0.92Pt0.08O3 has been treated at 850 degrees C for 40 h and subjected to NOx reduction at 350 degrees C for 200 h; the perovskite structure is well maintained in the process. The addition of 10 vol % H2O lowers NO conversion to about 77%, but the removal of water from the reaction gas immediately raises NO conversion to 90%.
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JOURNAL OF PHYSICAL CHEMISTRY C
ISSN: 1932-7447
Year: 2014
Issue: 25
Volume: 118
Page: 13743-13751
4 . 7 7 2
JCR@2014
3 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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