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Abstract:
Isobaric vapor-liquid equilibrium (VLE) data for three binary systems (PM + PMA, MeAc + PM and MeOH + PMA) at 101.3 kPa were measured in a double circulating still of modified Othmer type. The thermodynamic consistency of the experimental data was checked by Herington method. The experimental data were correlated with NRTL and Wilson models. The binary interaction parameters of both models have been obtained by simplex method. The root mean square deviations (RMSD) for the vapor phase fraction and the boiling temperature are less than 0.01 and 0.5 K, respectively. The results indicate that the calculated values by NRTL and Wilson models are in good agreement with the experimental data and no azeotropic behavior has been found in the three binary systems. The research findings would provide basic data for the design and analysis of distillation process. (C) 2014 Elsevier B.V. All rights reserved.
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FLUID PHASE EQUILIBRIA
ISSN: 0378-3812
Year: 2014
Volume: 367
Page: 45-50
2 . 2
JCR@2014
2 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:2
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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