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author:

Wang, Sibo (Wang, Sibo.) [1] (Scholars:汪思波) | Lin, Jinliang (Lin, Jinliang.) [2] | Wang, Xinchen (Wang, Xinchen.) [3] (Scholars:王心晨)

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Abstract:

A noble-metal-free system for photochemical reduction of CO2 has been developed by integrating graphitic carbon nitride (g-C3N4) with a cobalt-containing zeolitic imidazolate framework (Co-ZIF-9). g-C3N4 acts as a semiconductor photocatalyst, whereas Co-ZIF-9 is a cocatalyst that facilitates the capture/ concentration of CO2 and promotes light-induced charge separation. The two materials cooperate efficiently to catalyze CO2-to-CO conversion upon visible light illumination under mild reaction conditions. A C-13-labelled isotropic experiment proved that CO2 is the carbon source of the produced CO. Even without noble metals, the system still achieved an apparent quantum yield of 0.9 percent. The system displayed high photocatalytic stability, without noticeable alterations in the chemical and crystal structures of g-C3N4 and Co-ZIF-9 after the reaction.

Keyword:

Community:

  • [ 1 ] [Wang, Xinchen]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 2 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 王心晨

    [Wang, Xinchen]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

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Source :

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ISSN: 1463-9076

Year: 2014

Issue: 28

Volume: 16

Page: 14656-14660

4 . 4 9 3

JCR@2014

2 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:268

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 252

SCOPUS Cited Count: 270

ESI Highly Cited Papers on the List: 17 Unfold All

  • 2022-5
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  • 2020-11
  • 2020-9
  • 2020-5
  • 2020-3
  • 2020-1
  • 2019-9
  • 2019-5
  • 2019-3

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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