A　poly(dimethylsiloxane)　(PDMS)　stamp　was　electrolessly　plated　using　a　cyanide-free　solution.　Gold　nanoparticles　(AuNPs)　were　transferred　from　the　PDMS　stamp　to　indium　tin　oxide　(ITO),　(3-mercaptopropyl)　trimethoxysilane　modified　ITO　(MPTMS/ITO),　and　an　ITO　substrate　electrodeposited　with　a　thin　copper　film　(Cu/ITO).　AuNPs　formed　well-ordered　structures　which　were　characterized　by　field　emission　scanning　electron　microscopy　(FE-SEM),　atomic　force　microscopy　(AFM),　and　Raman　spectroscopy.　Microcontact　printing　allowed　thin　AuNPs　films　to　be　directly　transferred　from　PDMS　to　substrate,　so　is　a　simple,　fast,　cheap　and　environmentally-friendly　technique.　AuNPs　patterned　on　the　ITO　substrate　exhibited　surface-enhanced　Raman　spectroscopy　(SERS)　activity　which　will　be　investigated　in　subsequent　studies.