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Abstract:
Two zinc arsonate coordination polymers, Zn(4-apa)center dot H2O (1, 4-apaH(2) = 4-aminophenylarsonatic acid) and Zn(4-apa) (2), have been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal and powder X-ray diffraction. Crystal data for 1: monoclinic, space group C2/c with a = 23.056(5), b = 5.4224(11), c = 15.027(3) angstrom, beta = 121.22(3)degrees, V = 1606.6(6) angstrom(3), D-c = 2.468 g.cm(-3), F(000) = 1168, mu = 7.122 mm(-1), Z = 8, the final R = 0.0309 and wR = 0.0752 for 1763 observed reflections with I > 2 sigma(I). For 2: monoclinic, space group P2(1)/c with a = 8.7852(18), b = 9.2744(19), c = 9.752(2) angstrom, beta =103.45(3)degrees, V = 772.7(3) angstrom(3), D-c = 2.410 g.cm(-3), F(000) = 544, mu = 7.387 mm(-1), Z = 4, the final R = 0.0321 and wR = 0.0741 for 1696 observed reflections with I > 2 sigma(I). The structure of 1 shows a two-dimensional (4,4)-network composed of an inorganic ladder chain bridged by the phenyl-linkers of 4-apa ligands. Compound 2 exhibits a 3D layer-pillared framework with crb net, in which inorganic (4.8(2))-networks are joined by the phenyl-linkers.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2012
Issue: 9
Volume: 31
Page: 1301-1308
0 . 4 0 5
JCR@2012
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 5
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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