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author:

Lin Wen-Zhao (Lin Wen-Zhao.) [1] | Liu Zhong-Qian (Liu Zhong-Qian.) [2] | Huang Xi-He (Huang Xi-He.) [3] (Scholars:黄细河) | Li Hao-Hong (Li Hao-Hong.) [4] (Scholars:李浩宏) | Wu Shu-Ting (Wu Shu-Ting.) [5] (Scholars:吴舒婷) | Huang Chang-Cang (Huang Chang-Cang.) [6] (Scholars:黄长沧)

Indexed by:

SCIE CSCD

Abstract:

Two zinc arsonate coordination polymers, Zn(4-apa)center dot H2O (1, 4-apaH(2) = 4-aminophenylarsonatic acid) and Zn(4-apa) (2), have been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal and powder X-ray diffraction. Crystal data for 1: monoclinic, space group C2/c with a = 23.056(5), b = 5.4224(11), c = 15.027(3) angstrom, beta = 121.22(3)degrees, V = 1606.6(6) angstrom(3), D-c = 2.468 g.cm(-3), F(000) = 1168, mu = 7.122 mm(-1), Z = 8, the final R = 0.0309 and wR = 0.0752 for 1763 observed reflections with I > 2 sigma(I). For 2: monoclinic, space group P2(1)/c with a = 8.7852(18), b = 9.2744(19), c = 9.752(2) angstrom, beta =103.45(3)degrees, V = 772.7(3) angstrom(3), D-c = 2.410 g.cm(-3), F(000) = 544, mu = 7.387 mm(-1), Z = 4, the final R = 0.0321 and wR = 0.0741 for 1696 observed reflections with I > 2 sigma(I). The structure of 1 shows a two-dimensional (4,4)-network composed of an inorganic ladder chain bridged by the phenyl-linkers of 4-apa ligands. Compound 2 exhibits a 3D layer-pillared framework with crb net, in which inorganic (4.8(2))-networks are joined by the phenyl-linkers.

Keyword:

arsonate crystal structure synthesis zinc

Community:

  • [ 1 ] [Lin Wen-Zhao]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] [Liu Zhong-Qian]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [Huang Xi-He]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Li Hao-Hong]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wu Shu-Ting]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 6 ] [Huang Chang-Cang]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 黄细河

    [Huang Xi-He]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2012

Issue: 9

Volume: 31

Page: 1301-1308

0 . 4 0 5

JCR@2012

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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