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Abstract:
Ag-Ru/CeO2 catalysts were prepared by co-precipitation (CP), modified deposition precipitation (MDP), and incipient-wetness impregnation (IP). The obtained catalysts were characterized by N-2 physisorption, X-ray diffraction (XRD), H-2 temperature-programmed reduction (H-2-TPR), and temperature-programmed desorption of nitrogen (N-2-TPD). The results showed that the ammonia synthesis activity of the Ag-Ru/CeO2 catalyst prepared by incipient-wetness impregnation was 9.4% at 10 MPa, 10000 h(-1) and 400 degrees C, which was higher than that obtained by other methods. There were obvious differences in the reduction property of Ru/CeO2 and in the nitrogen dissociation behavior among the catalysts prepared by different methods. Catalyst activity for the catalyst prepared by incipient-wetness impregnation improved greatly at a low reaction temperature. The high catalytic activity was due to the easier reduction of Ag-Ru/CeO2 and the higher amount of dissociation of chemisorbed nitrogen.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
CN: 11-1892/O6
Year: 2011
Issue: 11
Volume: 27
Page: 2646-2650
0 . 7 8
JCR@2011
1 0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 4
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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