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author:

Zhang Liu-Ming (Zhang Liu-Ming.) [1] | Lin Jian-Xin (Lin Jian-Xin.) [2] (Scholars:林建新) | Wang Rong (Wang Rong.) [3] (Scholars:王榕) | Wei Ke-Mei (Wei Ke-Mei.) [4]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

Ag-Ru/CeO2 catalysts were prepared by co-precipitation (CP), modified deposition precipitation (MDP), and incipient-wetness impregnation (IP). The obtained catalysts were characterized by N-2 physisorption, X-ray diffraction (XRD), H-2 temperature-programmed reduction (H-2-TPR), and temperature-programmed desorption of nitrogen (N-2-TPD). The results showed that the ammonia synthesis activity of the Ag-Ru/CeO2 catalyst prepared by incipient-wetness impregnation was 9.4% at 10 MPa, 10000 h(-1) and 400 degrees C, which was higher than that obtained by other methods. There were obvious differences in the reduction property of Ru/CeO2 and in the nitrogen dissociation behavior among the catalysts prepared by different methods. Catalyst activity for the catalyst prepared by incipient-wetness impregnation improved greatly at a low reaction temperature. The high catalytic activity was due to the easier reduction of Ag-Ru/CeO2 and the higher amount of dissociation of chemisorbed nitrogen.

Keyword:

Ammonia synthesis Ceria Incipient-wetness impregnation Ru Silver

Community:

  • [ 1 ] [Zhang Liu-Ming]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Lin Jian-Xin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 林建新

    [Lin Jian-Xin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2011

Issue: 11

Volume: 27

Page: 2646-2650

0 . 7 8

JCR@2011

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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