mpg-C3N4-Catalyzed Selective Oxidation of Alcohols Using O-2 and Visible Light - Details

author：

Su, Fangzheng (Su, Fangzheng.) ^[1] | Mathew, Smitha C. (Mathew, Smitha C..) ^[2] | Lipner, Grzegorz (Lipner, Grzegorz.) ^[3] | Fu, Xianzhi (Fu, Xianzhi.) ^[4] (Scholars：付贤智) | Antonietti, Markus (Antonietti, Markus.) ^[5] | Blechert, Siegfried (Blechert, Siegfried.) ^[6] | Wang, Xinchen (Wang, Xinchen.) ^[7] (Scholars：王心晨)

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EI Scopus SCIE

Abstract：

Mesoporous　carbon　nitride　(mpg-C3N4)　polymer　can　function　as　a　metal-free　photocatalyst　to　activate　O-2　for　the　selective　oxidation　of　benzyl　alcohols　with　visible　light,　avoiding　the　cost,　toxicity,　and　purification　problems　associated　with　corresponding　transition-metal　systems.　By　combining　the　surface　basicity　and　semiconductor　functions　of　mpg-C3N4,　the　photocatalytic　system　can　realize　a　high　catalytic　selectivity　to　generate　benzaldehyde.　The　metal-free　photocatalytic　system　also　selectively　converts　other　alcohol　substrates　to　their　corresponding　aldehydes/ketones,　demonstrating　a　potential　pathway　of　accessing　traditional　mild　radical　chemistry　with　nitroxyl　radicals.

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Community：

[ 1 ] [Mathew, Smitha C.]Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[ 2 ] [Lipner, Grzegorz]Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[ 3 ] [Blechert, Siegfried]Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[ 4 ] [Su, Fangzheng]Fuzhou Univ, Int Joint Lab, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
[ 5 ] [Fu, Xianzhi]Fuzhou Univ, Int Joint Lab, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
[ 6 ] [Wang, Xinchen]Fuzhou Univ, Int Joint Lab, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
[ 7 ] [Su, Fangzheng]Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[ 8 ] [Antonietti, Markus]Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[ 9 ] [Wang, Xinchen]Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany

Reprint 's Address：

[Blechert, Siegfried]Tech Univ Berlin, Inst Chem, Str 17 Juni 135, D-10623 Berlin, Germany

Email：

blechert@chem.tu-berlin.de |
xcwang@fzu.edu.cn

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Mpg-C3N4-catalyzed selective oxidation of alcohols using O2 and visible light
2010，Journal of the American Chemical Society
Mpg-C3N4-catalyzed selective oxidation of alcohols using O2 and visible light
2010，Journal of the American Chemical Society

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Source ：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ISSN： 0002-7863

Year： 2010

Issue： 46

Volume： 132

Page： 16299-16301

9 . 0 2 3

JCR@2010

1 4 . 5 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 21 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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