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author:

Xie, Li-Li (Xie, Li-Li.) [1] (Scholars:谢莉莉) | Favre-Reguillon, Alain (Favre-Reguillon, Alain.) [2] | Wang, Xu-Xu (Wang, Xu-Xu.) [3] (Scholars:王绪绪) | Fu, Xianzhi (Fu, Xianzhi.) [4] (Scholars:付贤智) | Lemaire, Marc (Lemaire, Marc.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

Adsorptive removal of hydrodesulfurization inhibitors, that is, nitrogen-containing compounds (N-compounds), was studied using model fuel which contains carbazole and dibenzothiophene in an n-dodecane-toluene mixture over ion-exchange resins (IXRs) in batch and in fixed-bed adsorption systems. The adsorptive capacity and selectivity for neutral N-compounds were examined. The high affinity for neutral N-compounds present in hydrocarbon feed was explained by hydrogen bonding between the chloride anion (with nonbonding electrons) and the neutral N-compounds. However, the presence of a flat charged cation, that is, N-alkylated pyridinium, is essential to ensure the adsorption of neutral N-compounds. The regeneration of the sorbent could be easily performed using polar organic solvent like methanol. Commercially available IXR bearing pyridinium chloride functionality (HPQ) was further evaluated with straight-run fuel oil. The N/S selectivity decreases, but analysis of the adsorbed compounds by gas chromatography/mass spectroscopy (GC/MS) shows that no paraffin and no monoaromatics were adsorbed. The results obtained provided new insight into the fundamental understanding of the adsorption mechanism of neutral N-compounds from hydrocarbon feed.

Keyword:

Community:

  • [ 1 ] [Xie, Li-Li]Univ Lyon 1, ICBMS, UMR 5246, Lab Catalyse & Synth Organ, F-69622 Villeurbanne, France
  • [ 2 ] [Favre-Reguillon, Alain]Univ Lyon 1, ICBMS, UMR 5246, Lab Catalyse & Synth Organ, F-69622 Villeurbanne, France
  • [ 3 ] [Lemaire, Marc]Univ Lyon 1, ICBMS, UMR 5246, Lab Catalyse & Synth Organ, F-69622 Villeurbanne, France
  • [ 4 ] [Xie, Li-Li]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wang, Xu-Xu]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 7 ] [Favre-Reguillon, Alain]Conservatoire Natl Arts & Metiers, Lab Transformat Chim & Pharmaceut, F-75003 Paris, France

Reprint 's Address:

  • [Favre-Reguillon, Alain]Univ Lyon 1, ICBMS, UMR 5246, Lab Catalyse & Synth Organ, 43 Blvd 11 Novembre 1918, F-69622 Villeurbanne, France

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Source :

JOURNAL OF CHEMICAL AND ENGINEERING DATA

ISSN: 0021-9568

Year: 2010

Issue: 11

Volume: 55

Page: 4849-4853

2 . 0 8 9

JCR@2010

2 . 0 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 54

SCOPUS Cited Count: 62

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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