A lead(II)-orotate coordination polymer with a new coordination mode: Synthesis, structure and luminescent property - Details

author：

Yin, Hua (Yin, Hua.) ^[1] (Scholars：尹华) | Liu, Shi-Xiong (Liu, Shi-Xiong.) ^[2]

Indexed by：

Scopus SCIE

Abstract：

A　lead(II)　orotate　complex　[Pb(HOr)(H2O)](n)　(1),　(H3Or　=　orotic　acid)　was　synthesized　under　hydrothermal　condition　and　characterized　by　X-ray　diffraction,　IR,　solid-state　photoluminescence　and　thermogravimetric　analysis.　Lead　atom　in　1　is　in　a　holodirected　eight-coordinated　polyhedron　and　the　orotate　ligand　exhibits　a　new　and　unique　hexametallic　coordination　mode.　The　lead　complex　shows　a　6,6-connected　(4(8),　6(6).8)(4(13).6(2))　topology.　The　complex　exhibits　photoluminescence　at　546　nm　(lambda(ex)　=　350　nm).　(c)　2008　Elsevier　B.V.　All　rights　reserved.

Keyword：

Complex Crystal structure Lead(II) Luminescent property Topology

Community：

[ 1 ] [Liu, Shi-Xiong]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
[ 2 ] [Liu, Shi-Xiong]Fuzhou Univ, Instrumental Measurement & Anal Ctr, Fuzhou 350002, Peoples R China

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