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author:

Chen, XH (Chen, XH.) [1] (Scholars:陈晓晖) | Fan, ZY (Fan, ZY.) [2] | Quan, X (Quan, X.) [3] | Wei, KM (Wei, KM.) [4]

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Scopus SCIE PKU CSCD

Abstract:

Ti-MWW was prepared by acid treatment and calcination on a lamellar precursor which was synthesized under dynamic hydrothermal crystallization conditions using piperidine as a template, and boric acid as a stucture-supporting agent. The crystallization time is shortened by adding Ti-MWW seeds and increasing stirring rate. Ultraviolet-visible spectra show that the precursor contains tetrahedral and octahedral Ti species. Calcination of the precursor results in a partial condensation of the octahedral Ti to form the anatase phase. The octahedral Ti species belong to a kind of extraframework Ti, which can be removed easily by the acid treatment in a short time. The calcined Ti-MWW contains the anatase when the acid-treated time is too long. The characteristic infrared band at 960 cm(-1) is not observed for the Ti-MWW precursor, but it appears in the samples treated by acid. Epoxidation of allyl alcohol with H2O2 on Ti-MWW was studied. Ti-MWW with Si/Ti ratio of 20 and acid treatment for 12 similar to 16 h is more effective. The conversation of allyl alcohol is 88.7%, and the selectivity for glycidol is 99% under the reaction conditions of 333 K and 30 min, but the catalytic activity of Ti-MWW decreases when the acid-treated time is too long.

Keyword:

allyl alcohol epoxidation glycidol Ti-MWW molecular sieve

Community:

  • [ 1 ] Fuzhou Univ, Coll Chem & Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fujian 350002, Peoples R China

Reprint 's Address:

  • 陈晓晖

    [Chen, XH]Fuzhou Univ, Coll Chem & Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fujian 350002, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2006

Issue: 3

Volume: 27

Page: 285-290

0 . 6 5 9

JCR@2006

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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