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author:

Hua, JM (Hua, JM.) [1] (Scholars:华金铭) | Zheng, Q (Zheng, Q.) [2] (Scholars:郑起) | Zheng, YH (Zheng, YH.) [3] (Scholars:郑远辉) | Wei, KM (Wei, KM.) [4] | Lin, XY (Lin, XY.) [5] (Scholars:林性贻)

Indexed by:

EI Scopus SCIE

Abstract:

The activity and stability of Au/ Fe2O3 - MOx catalysts ( M = Zr, Mg, Ca, Ni, La, Cu, Zn, Al, Ba, Cr, Co, Ce, Mo, Bi, Ti, Mn) in water- gas shift reaction were investigated extensively. The WGS activity and stability of Au/ Fe2O3 is improved significantly upon addition of ZrO2 and to a lesser extend MgO, CaO, NiO, La2O3, Cr2O3, CuO. In contrast, Bi, Ti and Mn oxides seriously decrease the catalytic activity while additions of Zn, Al, Ba, Co, Ce and Mo oxides do not influence evidently the catalytic activity and its stability. Based on the characterization using the methods of BET- surface area and pore structure XRF, XRD, and H-2 - TPR for some of as- prepared and spent samples, it could be concluded that the catalytic activity of gold catalysts supported on composite oxide of Fe2O3 - MOx depends not only on the dispersion of the gold particles but also on the reduction property of composite oxide supports, regardless of the fluctuation of gold loading and some change of specific surface area and pore structure due to introduction of the modifying metal oxides. The improvement of catalytic stability may be attributed to the comparative stabilization of high dispersion of gold particles and uneasily sintering of Fe3O4 crystallites during the catalytic operation. However, the chemical ( electronic) effects exerted by the modifying addition of metal oxides on the catalytic performance of gold catalyst may not be ruled out.

Keyword:

catalytic stability gold catalyst iron oxide metal oxides modification water-gas shift

Community:

  • [ 1 ] Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Fujian 350002, Peoples R China
  • [ 2 ] Zijin Min Grp Co Ltd, Zijin Res Engn Inst Min & Met, Fujian 364200, Peoples R China
  • [ 3 ] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China

Reprint 's Address:

  • 郑起

    [Zheng, Q]Fuzhou Univ, Natl Res Ctr Chem Fertilizer Catalysts, Gongye Rd 523, Fujian 350002, Peoples R China

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Source :

CATALYSIS LETTERS

ISSN: 1011-372X

Year: 2005

Issue: 1-2

Volume: 102

Page: 99-108

2 . 0 8 8

JCR@2005

2 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 38

SCOPUS Cited Count: 42

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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