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author:

Cao, YN (Cao, YN.) [1] (Scholars:曹彦宁) | Zhang, HH (Zhang, HH.) [2] | Huang, CC (Huang, CC.) [3] (Scholars:黄长沧) | Sun, YX (Sun, YX.) [4] | Chen, YP (Chen, YP.) [5] (Scholars:陈义平) | Guo, WJ (Guo, WJ.) [6] | Zhang, FL (Zhang, FL.) [7]

Indexed by:

SCIE PKU CSCD

Abstract:

The title compound (H3NCH2CH2NH3)(4)[(VO)(6)(B10O22)(2)] (H3O)(7) 1 has been synthesized by the hydrothermal method and determined by X-ray crystallography. Crystallographic data: monoclinic, space group C2/c, a 20.250(4), b = 13.448(3), c = 21.655(4) angstrom, beta = 97.05(3)degrees, M, 851.74 (C4H30.5B10N40O28.5V3), V = 5852(2) angstrom(3), Z = 8, D-c = 1.933 g/cm(3), mu = 1.057 mm(-1), F(000) 3436, R = 0.0500 and wR = 0.1442 for 4511 observed reflections with I > 2 sigma(I). The structure consists of [(VO)(6)(B10O22)(2)](15-) cluster anions that have a central band of six trans-edge-sharing VO5 square pyramids capped by two [B10O22](14-) poly borate ligands. Other characterizations are also described by elemental analysis, IR spectrum and thermal analysis.

Keyword:

crystal structure hydrothermal synthesis polyoxovanadium borate

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] Qufu Normal Univ, Coll Chem Sci, Qufu 273165, Peoples R China

Reprint 's Address:

  • 张汉辉

    [Zhang, HH]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2005

Issue: 5

Volume: 24

Page: 525-530

0 . 6 6 9

JCR@2005

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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