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Abstract:
The title compound (H3NCH2CH2NH3)(4)[(VO)(6)(B10O22)(2)] (H3O)(7) 1 has been synthesized by the hydrothermal method and determined by X-ray crystallography. Crystallographic data: monoclinic, space group C2/c, a 20.250(4), b = 13.448(3), c = 21.655(4) angstrom, beta = 97.05(3)degrees, M, 851.74 (C4H30.5B10N40O28.5V3), V = 5852(2) angstrom(3), Z = 8, D-c = 1.933 g/cm(3), mu = 1.057 mm(-1), F(000) 3436, R = 0.0500 and wR = 0.1442 for 4511 observed reflections with I > 2 sigma(I). The structure consists of [(VO)(6)(B10O22)(2)](15-) cluster anions that have a central band of six trans-edge-sharing VO5 square pyramids capped by two [B10O22](14-) poly borate ligands. Other characterizations are also described by elemental analysis, IR spectrum and thermal analysis.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2005
Issue: 5
Volume: 24
Page: 525-530
0 . 6 6 9
JCR@2005
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
Cited Count:
WoS CC Cited Count: 12
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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