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author:

Xu, XP (Xu, XP.) [1] (Scholars:许小平) | Huther, A (Huther, A.) [2] | Maurer, G (Maurer, G.) [3]

Indexed by:

SCIE CSCD

Abstract:

N-isopropylacrylamide (NIPAAm) was used to synthesize NIPAAm homopolymer (nonionized) and NIPAAm-sodium methacrylate copolymer (ionized). The swelling equilibria for both gels were obtained in aqueous solution of ethanol with concentration ranging from 0 to 100%(by mass) at 25degreesC. The swollen gel in water shrank first with the addition of a small amount of ethanol and then reswelled with further addition of ethanol showing not only a discontinuous volume phase transition but also a typical reentrant phenomenon. A thermodynamic model based on the UNIQUAC with the "free-volume" contribution was applied to correlate and predict the swelling behavior of the poly(NIPAAM)-gels in ethanol-water mixture.

Keyword:

hydrogel model poly(N-isopropylacrylamide) swelling

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67663 Kaiserslautern, Germany

Reprint 's Address:

  • 许小平

    [Xu, XP]Fuzhou Univ, Dept Chem Engn, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF CHEMICAL ENGINEERING

ISSN: 1004-9541

CN: 11-3270/TQ

Year: 2003

Issue: 3

Volume: 11

Page: 264-268

0 . 3 5 7

JCR@2003

3 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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