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Abstract：
A novel molybdophosphate supermolecular compound (bipyH(2))(2)(H2P2Mo5O23) . H2O has been synthesized by hydrothermal method and characterized by crystal X-ray structure analysis, IR spectrum, Raman spectrum, UV-Vis DRIS spectrum, fluorescence spectrum and CV. The crystal belongs to monoclinic system with a space group P2(1)/c, a = 1.679 51(7) nm, b = 1.151 93(4) nm, c = 1. 889 08(8) nm, beta = 108. 335(1)degrees, V= 3. 469 2(2) nm(3), Z = 4, D-c = 2.382 g/cm(3), F(000) = 2 408, mu = 1. 951 mm(-1), R = 0.024 4, R-w = 0.072 1. The heteropoly anion [H2P2Mo5O23](4-) and protonated 4,4＇-bipy are connected to a supermolecular compound by hydrogen bonds; and the anions contain five MoO6 octahedra and two PO4 tetrahedron; Mo, P atoms show a distorted pentagonal bipyramidal configuration, and the heteropoly anions are connected to a infinite planar structure with the protonated 4,4＇-bipy.
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Chemical Journal of Chinese Universities
ISSN： 0251-0790
CN： 22-1131/O6
Year： 2002
Issue： 4
Volume： 23
Page： 521-525
0 . 8 3
JCR@2002
0 . 7 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
JCR Journal Grade：2
Cited Count：
WoS CC Cited Count： 23
SCOPUS Cited Count：
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 1
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